Enhanced Tensile Properties of Multi-Walled Carbon Nanotubes Filled Polyamide 6 Composites Based on Interface Modification and Reactive Extrusion

Title
Enhanced Tensile Properties of Multi-Walled Carbon Nanotubes Filled Polyamide 6 Composites Based on Interface Modification and Reactive Extrusion
Authors
박민박종혁유재상Ji-un JangSeong Yun Kim
Keywords
polymer-matrix composites; carbon nanotubes; micro-mechanics
Issue Date
2020-04
Publisher
Polymers
Citation
VOL 12, NO 5, 997
Abstract
To induce uniform dispersion and excellent interfacial properties, we adopted a strategy of combining both polyamide 6 (PA6) grafting for multi-walled carbon nanotubes (MWCNTs) and reactive extrusion of PA6 matrix, based on anionic ring-opening polymerization of ε-caprolactam (CL). Compared to -COOH and -NCO treatments of MWCNTs, enhanced MWCNT dispersion and tensile properties of the composites were achieved using the applied strategy, and the tensile strength and modulus of the PA6-grafted MWCNT-filled PA6 composites were 5.3% and 20.5% higher than those of the purified MWCNT-filled PA6 composites, respectively. In addition, they were almost similar to the theoretical ones calculated by the modified Mori-Tanaka method (MTM) assuming a perfect interface, indicating that the tensile properties of MWCNT-filled PA6 composites can be optimized by PA6 grafting and reactive extrusion based on the anionic ring-opening polymerization of CL due to uniform MWCNT dispersion and excellent interfacial property.
URI
http://pubs.kist.re.kr/handle/201004/71355
ISSN
2073-4360
Appears in Collections:
KIST Publication > Article
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