Study on the unsteady state oxidative coupling of methane: effects of oxygen species from O2, surface lattice oxygen, and CO2 on the C2+ selectivity

Title
Study on the unsteady state oxidative coupling of methane: effects of oxygen species from O2, surface lattice oxygen, and CO2 on the C2+ selectivity
Authors
서동진최재욱하정명윤수지임서연Kwang Ho Song
Issue Date
2020-10
Publisher
RSC advances
Citation
VOL 10, NO 59-35897
Abstract
This study examined the effects of oxygen species on the unsteady-state oxidative coupling of methane (OCM) using a lengthy catalyst bed of Na2WO4/Mn/SiO2. The reaction conditions, including the methane-to-oxygen ratio, ratio of feed gas dilution by N2, quantity of catalyst, and feed flow rate were adjusted for the continuous flow fixed bed reaction system. While the O2 gas initiated methyl radical formation from methane, the surface lattice oxygen atoms improved the dehydrogenation of paraffins to olefins without significant activation of methane. The addition of CO2 as a mild oxidizing agent was also tested and slightly improved OCM selectivity with slightly lower methane conversion were observed.
URI
http://pubs.kist.re.kr/handle/201004/71888
ISSN
2046-2069
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KIST Publication > Article
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