Graphene oxide nanoribbon hydrogel: viscoelastic behavior and use as a molecular separation membrane

Title
Graphene oxide nanoribbon hydrogel: viscoelastic behavior and use as a molecular separation membrane
Authors
김성수최윤규김지훈강준혁최은지최승은김정필권오찬김대우
Issue Date
2020-09
Publisher
ACS Nano
Citation
VOL 14, NO 9-12202
Abstract
The preparation of carbon materials based hydrogels and their viscoelastic properties are essential for their broad application and scale-up. However, existing studies are mainly focused on graphene derivatives and carbon nanotubes, and the behavior of graphene nanoribbon (GNR), a narrow strip of graphene, remains elusive. Herein, we demonstrate the concentration-driven gelation of oxidized GNR (graphene oxide nanoribbon, GONR) in aqueous solvents. Exfoliated individual GONRs sequentially assemble into strings (∼1 mg/mL), nanoplates (∼20 mg/mL), and a macroporous scaffold (50 mg/mL) with increasing concentration. The GONR hydrogels exhibit viscoelastic shear-thinning behavior and can be shear-coated to form large-area GONR films on substrates. The entangled and stacked structure of the GONR film contributed to outstanding nanofiltration performance under high pressure, cross-flow, and long-term filtration, while the precise molecular separation with 100% rejection rate was maintained for sub-nanometer molecules.
URI
http://pubs.kist.re.kr/handle/201004/72418
ISSN
1936-0851
Appears in Collections:
KIST Publication > Article
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