Li, Shi Jang, Jae Hong Chung, Wookjin Seung, Hyojin Park, Soo Ik Ma, Hyeonjong Pyo, Won Jun Choi, Changsoon Chung, Dae Sung Kim, Dae-Hyeong Choi, Moon Kee Yang, Jiwoong 2024-01-19T08:31:43Z 2024-01-19T08:31:43Z 2023-11-01 2023-10 1936-0851 https://pubs.kist.re.kr/handle/201004/113193 Mechanically deformable photodetectors (PDs) are key device components for wearable health monitoring systems based on photoplethysmography (PPG). Achieving high detectivity, fast response time, and an ultrathin form factor in the PD is highly needed for next-generation wearable PPG systems. Self-powered operation without a bulky power-supply unit is also beneficial for point-of-care application. Here, we propose ultrathin self-powered PDs using heavy-metal-free Cu-In-Se quantum dots (QDs), which enable high-performance wearable PPG systems. Although the light-absorbing QD layer is extremely thin (similar to 40 nm), the developed PD exhibits excellent performance (specific detectivity: 2.10 x 10(12) Jones, linear dynamic range: 102 dB, and spectral range: 250-1050 nm at zero bias), which is comparable to that of conventional rigid QD-PDs employing thick Pb-chalcogenide QD layers. This is attributed to material and device strategies-materials that include Cu-In-Se QDs, a MoS2-nanosheet-blended poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) hole transport layer, a ZnO nanoparticle electron transport layer, Ag and ITO electrodes, and an ultrathin form factor (similar to 120 nm except the electrodes) that enable excellent mechanical deformability. These allow the successful application of QD-PDs to a wearable system for real-time PPG monitoring, expanding their potential in the field of mobile bioelectronics. English American Chemical Society Ultrathin Self-Powered Heavy-Metal-Free Cu-In-Se Quantum Dot Photodetectors for Wearable Health Monitoring Article 10.1021/acsnano.3c05178 1 ACS Nano, v.17, no.20, pp.20013 - 20023 ACS Nano 17 20 20013 20023 N scie scopus 001077696500001 Chemistry, Multidisciplinary Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Science & Technology - Other Topics Materials Science Article SENSORS ARRAYS NANOCRYSTALS ABSORPTION heavy-metal-free quantumdots wearable electronics self-powered photodetectors photoplethysmography