Hasan, Rahidul Gu, Yan Kim, Se Yun Chun, Dong Won Lee, Kyu Hyoung 2024-01-19T08:32:25Z 2024-01-19T08:32:25Z 2023-09-07 2023-10 https://pubs.kist.re.kr/handle/201004/113224 Double half-Heuslers (DHHs) have emerged as promising candidates for thermoelectric power generation at mid-high temperatures due to their exceptional chemical and mechanical stability, as well as high electronic transport properties. However, their limited thermoelectric conversion efficiency (ZT) has hindered their practical application. In the present study, we propose an approach to enhance the ZT of DHHs by generating full-Heusler (FH) nanoprecipitates through a simple and scalable compositional tuning method. We investigate the effectiveness of this approach using Ti2FeNiSb2 as a model system. Our results reveal that FH nanoprecipitates can substantially intensify the phonon scattering in Ti2FeNiSb2, leading to an ultra-low lattice thermal conductivity of similar to 0.9 W m(-1) K-1 at 973 K. Additionally, filtering of low-energy carriers, in the presence of FH nanoprecipitates, further improves the electronic transport properties. As a result, we achieved a relatively high zT of 0.31 in Ti2FeNi1.05Sb2, which is 1.5-fold enhancement compared to the pristine Ti2FeNiSb2. These findings offer attractive opportunities for designing and developing high-performance DHH-based thermoelectric materials. English Royal Society of Chemistry Enhancing the thermoelectric performance of a Ti2FeNiSb2 double half-Heusler alloy through excess Ni-induced full-Heusler nanoprecipitates Article 10.1039/d3qi01132a 1 Inorganic Chemistry Frontiers, v.10, no.19, pp.5662 - 5667 Inorganic Chemistry Frontiers 10 19 5662 5667 N scie scopus 001184914200001 Chemistry, Inorganic & Nuclear Chemistry Article LARGE ENHANCEMENTS CONDUCTIVITY THERMOPOWER FIGURE MERIT ZT