Min, Kyungwhan Al Munsur, Abu Zafar Paek, Sae Yane Jeon, Soomin Lee, So Young Kim, Tae-Hyun 2024-01-19T10:01:17Z 2024-01-19T10:01:17Z 2023-04-20 2023-03 1944-8244 https://pubs.kist.re.kr/handle/201004/113914 Proton exchange membrane water electrolysis (PEMWE) generates oxygen and hydrogen at the anode and cathode, respectively, by conducting protons generated at the anode to the cathode through a proton exchange membrane (PEM). The performance of PEMWE can be improved with faster catalytic reactions at each electrode; thus, the development of a PEM with excellent ionic conductivity and physicochemical stability is essential. Nafion, a type of perfluoro-sulfonic acid polymer, is the most widely used PEM material. However, despite its excellent conductivity and chemical stability, it exhibits high hydrogen permeability due to its structural characteristics. Quantum dots (QDs) have a hydrophilic functional group that can act as an ion conductor and are extremely compatible with the hydrophilic cluster of Nafion due to their characteristic nanosized structure. In this study, various compositions of N-doped carbon quantum dots (CQDs) containing hydrophilic functional groups were coated on a Nafion-212 membrane. The resulting series of CQD-coated Nafion membranes exhibited improvements in morphology and ionic conductivity as well as reductions in hydrogen permeability. In particular, the Nafion membrane coated with 0.75 wt % of N-doped CQD (CQD-cNafion-0.75) exhibited improved mechanical properties and higher oxidation stability compared to Nafion-212. It also displayed higher ionic conductivity of 240.3 mS cm-1 at 80 degrees C and reduced hydrogen permeability (about 10% reduction) compared to Nafion-212. In addition, the performance of single-cell PEMWE using the CQD-cNafion-0.75 membrane was found to be approximately 1.2 times higher than Nafion-212. English American Chemical Society Development of High-Performance Polymer Electrolyte Membranes through the Application of Quantum Dot Coatings to Nafion Membranes Article 10.1021/acsami.3c01289 1 ACS Applied Materials & Interfaces, v.15, no.12, pp.15616 - 15624 ACS Applied Materials & Interfaces 15 12 15616 15624 N scie scopus 000961454900001 2-s2.0-85150412318 Nanoscience & Nanotechnology Materials Science, Multidisciplinary Science & Technology - Other Topics Materials Science Article METHANOL FUEL-CELL OXIDE COMPOSITE MEMBRANES HIGH-TEMPERATURE GRAPHENE OXIDE CROSSOVER HYDROGEN IMPROVE LAYER proton exchange membrane water electrolysis polymer electrolyte membrane quantum dot coating proton conductivity