Noh, Gichang Song, Hwayoung Choi, Heenang Kim, Mingyu Jeong, Jae Hwan Lee, Yongjoon Choi, Min-Yeong Oh, Saeyoung Jo, Min-kyung Woo, Dong Yeon Jo, Yooyeon Park, Eunpyo Moon, Eoram Kim, Tae Soo Chai, Hyun-Jun Huh, Woong Lee, Chul-Ho Kim, Cheol-Joo Yang, Heejun Song, Senugwoo Jeong, Hu Young Kim, Yong-Sung Lee, Gwan-Hyoung Lim, Jongsun Kim, Chang Gyoun Chung, Taek-Mo Kwak, Joon Young Kang, Kibum 2024-01-19T11:02:29Z 2024-01-19T11:02:29Z 2022-09-22 2022-10 0935-9648 https://pubs.kist.re.kr/handle/201004/114502 Van der Waals (vdW) heterostructures have drawn much interest over the last decade owing to their absence of dangling bonds and their intriguing low-dimensional properties. The emergence of 2D materials has enabled the achievement of significant progress in both the discovery of physical phenomena and the realization of superior devices. In this work, the group IV metal chalcogenide 2D-layered Ge4Se9 is introduced as a new selection of insulating vdW material. 2D-layered Ge4Se9 is synthesized with a rectangular shape using the metalcorganic chemical vapor deposition system using a liquid germanium precursor at 240 degrees C. By stacking the Ge4Se9 and MoS2, vdW heterostructure devices are fabricated with a giant memory window of 129 V by sweeping back gate range of +/- 80 V. The gate-independent decay time reveals that the large hysteresis is induced by the interfacial charge transfer, which originates from the low band offset. Moreover, repeatable conductance changes are observed over the 2250 pulses with low non-linearity values of 0.26 and 0.95 for potentiation and depression curves, respectively. The energy consumption of the MoS2/Ge4Se9 device is about 15 fJ for operating energy and the learning accuracy of image classification reaches 88.3%, which further proves the great potential of artificial synapses. English WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Large Memory Window of van der Waals Heterostructure Devices Based on MOCVD-Grown 2D Layered Ge4Se9 Article 10.1002/adma.202204982 1 Advanced Materials, v.34, no.41 Advanced Materials 34 41 N scie scopus 000851968800001 Chemistry, Multidisciplinary Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Physics, Applied Physics, Condensed Matter Chemistry Science & Technology - Other Topics Materials Science Physics Article; Early Access CHARGE-TRANSFER BAND-OFFSET HYSTERESIS MOS2 GESE DYNAMICS PHASE charge transfer germanium selenide metal-organic chemical vapor deposition synaptic devices van der Waals heterostructures