Lee, Yong Min Jung, Byung Ku Ahn, Junhyuk Park, Taesung Shin, Chanho Ng, Tse Nga Kim, In Soo Choi, Ji-Hyuk Oh, Soong Ju 2024-01-19T11:03:05Z 2024-01-19T11:03:05Z 2022-07-21 2022-10 2199-160X https://pubs.kist.re.kr/handle/201004/114533 An effective surface-doping strategy for CdSe nanocrystals (NCs) by examining the size-dependency of the doping behavior is introduced. A CdSe NC thin-film transistor (TFT) is fabricated via a doping process with InCl3 treatment followed by an annealing process. Spectroscopic and electronic device characterization reveal that smaller NCs are more effectively doped than larger NCs at all annealing temperatures. This is attributed to the larger specific surface area, where the dopant can be more readily coordinated. The degenerate behavior of a 3.3 nm CdSe-NC TFT appears at a lower temperature than that of larger NC TFTs. High electron mobility and on-to-off current ratio of 1.79 cm(2) Vs(-1) and 5.2 x 10(5), respectively are achieved, in a low-temperature annealing process (150 degrees C) with 3.3 nm CdSe NCs. This facilitates the fabrication of a flexible CdSe-NC TFT, which is demonstrated on a polyethylene terephthalate substrate with an Al2O3 dielectric layer using atomic layer deposition. The flexible 3.3 nm CdSe-NC TFT is successfully fabricated even at 150 degrees C, with a high on-to-off current ratio and low hysteresis at a low operation voltage, which is impossible for larger CdSe-NC TFTs. English Wiley-VCH Verlag Development of Low-Temperature Doping Process in CdSe-Nanocrystal Thin Films for Flexible Electronic and Optoelectronic Devices Article 10.1002/aelm.202200297 1 Advanced Electronic Materials, v.8, no.10 Advanced Electronic Materials 8 10 N scie scopus 000824120900001 Nanoscience & Nanotechnology Materials Science, Multidisciplinary Physics, Applied Science & Technology - Other Topics Materials Science Physics Article COLLOIDAL NANOCRYSTALS TRANSISTORS TRANSPORT SIZE LIGANDS doping nanocrystals photodetectors semiconductors transistors