Ho, Van-Chuong Oh, Si Hyoung Mun, Junyoung 2024-01-19T12:01:46Z 2024-01-19T12:01:46Z 2022-04-03 2022-06 0363-907X https://pubs.kist.re.kr/handle/201004/115173 Manganese-based oxides are being actively studied as cathode materials for rechargeable aqueous zinc ion batteries (AZIBs) because of their high capacity, cost-effectiveness, safety, and eco-friendliness. Herein, we propose a binder-free electrode of bivalent manganese oxide with the chemical composition of Mn5O8 deposited on stainless steel as a cathode of AZIBs. Mn5O8 nanoparticles with a layered structure, which provide a facile pathway for Zn2+ ion transport and diffusion, were directly deposited on a three-dimensional stainless steel mesh via a hydrothermal method using different temperatures. The structures of the active materials in the cathode were characterized by X-ray diffraction, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and field-emission scanning electron microscopy. The Mn5O8 cathode materials exhibited a high specific capacity of 254.98 mAh g(-1), and simultaneously demonstrated satisfactory reversible charge/discharge and high rate performance. The Zn2+ insertion/extraction behaviors were studied in detail by cyclic voltammetry. In addition, factors that influence the electrochemical performance of the cathode, such as the phase structure and particle size of manganese dioxide, are discussed. Smaller and homogeneous Mn5O8 particles provide a large interface area and facilitate more zinc ions for diffusion, leading to improved ionic current and specific capacity. English John Wiley & Sons Inc. A binder-free bivalent manganese oxide cathode elective structure with high activity in aqueous zinc ion batteries Article 10.1002/er.7841 1 International Journal of Energy Research, v.46, no.7, pp.9720 - 9732 International Journal of Energy Research 46 7 9720 9732 N scie scopus 000770010700001 2-s2.0-85126345326 Energy & Fuels Nuclear Science & Technology Energy & Fuels Nuclear Science & Technology Article HIGH-CAPACITY NANOPARTICLES MN5O8 binder-free electrode elective structure high electrochemical activity high-energy density Mn5O8 cathode zinc aqueous battery