Kim, Y.-J. Han, K.-S. Lee, B.-H. 2024-01-19T12:38:03Z 2024-01-19T12:38:03Z 2022-03-07 2011-01 0255-5476 https://pubs.kist.re.kr/handle/201004/115718 Synthesis of gray ceramic pigment was carried out by doping cobalt on Tialite crystal structure. Tialite was synthesized by using Al2O 3 and TiO2, and was doped with Co3O4 as a chromophore material. To prevent the thermal decomposition during cooling procedure Fe2O3 was added by 0.05mole as a stabilizer. Samples were fired at 1400∼1500° for 2hours and cooled naturally. Crystal structure, solubility limit and color of synthesized pigment were analyzed by XRD, Raman spectroscopy, UV and UV-vis. Yield percentage of Tialite was 96.15% with using Fe2O3 as a stabilizer. It was found that solubility limit of Co2+ in Tialite crystal was 0.03 mole% through analysis of XRD and Raman. By adding pigment with 0.03 mole% of Co 2+ to lime-barium glaze, stabilized Dark Gray color glaze having 46.12, -1.26, 0.53 as CIE-L*a*b* was synthesized. ？ (2011) Trans Tech Publications. English ISEPD Synthesis of Co-doped tialite ceramic pigments and coloring in glazes Conference 10.4028/www.scientific.net/MSF.695.299 1 12th International Symposium on Eco-Materials Processing and Design (ISEPD2011), pp.299 - 302 12th International Symposium on Eco-Materials Processing and Design (ISEPD2011) 299 302 TH Chiang Mai, Thailand 2011-01-08 Materials Science Forum 2-s2.0-80053238538