Lee, Hyun-Wook Kim, Hun Jung, Hun-Gi Sun, Yang-Kook Kwak, Won-Jin 2024-01-19T13:34:13Z 2024-01-19T13:34:13Z 2021-10-21 2021-10 1616-301X https://pubs.kist.re.kr/handle/201004/116353 Lithium oxygen batteries (LOBs) are considered promising next-generation lithium batteries owing to their high theoretical specific energy density. However, several issues must be addressed for realizing the practical applications of LOBs. Among them, the evolution of singlet oxygen (O-1(2))-which undergoes vigorous reactions that compromise the stability of the system-is a key challenge. The high overpotential induced by low-conductivity lithium peroxide necessitates the use of a redox mediator (RM) to facilitate the charging process; however, RMs can also be degraded by O-1(2), which limits their efficacy in the long term. Recently, it was revealed that certain RMs play a role in suppressing the generation of O-1(2). In this review, the relationship between the RM and O-1(2) is described. Based on recent understandings, clear insight into RM reactions toward O-1(2) and possible future research directions will be provided. English WILEY-V C H VERLAG GMBH LITHIUM-OXYGEN BATTERIES REDOX MEDIATORS PROTECTIVE LAYER METAL ELECTROLYTES PEROXIDE ION SUPEROXIDE EVOLUTION Ambilaterality of RM towards O-1(2) in Li-O-2 Batteries: Trap and Quencher Article 10.1002/adfm.202102442 1 ADVANCED FUNCTIONAL MATERIALS, v.31, no.40 ADVANCED FUNCTIONAL MATERIALS 31 40 scie scopus 000669116600001 2-s2.0-85109196002 Chemistry, Multidisciplinary Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Physics, Applied Physics, Condensed Matter Chemistry Science & Technology - Other Topics Materials Science Physics Article LITHIUM-OXYGEN BATTERIES REDOX MEDIATORS PROTECTIVE LAYER METAL ELECTROLYTES PEROXIDE ION SUPEROXIDE EVOLUTION lithium-oxygen batteries redox mediators singlet oxygen