Jung, Wo Dum Jeon, Minjae Shin, Sung Soo Kim, Ji-Su Jung, Hun-Gi Kim, Byung-Kook Lee, Jong-Heun Chung, Yong-Chae Kim, Hyoungchul 2024-01-19T16:31:24Z 2024-01-19T16:31:24Z 2021-09-02 2020-10-13 2470-1343 https://pubs.kist.re.kr/handle/201004/117997 Sulfide solid electrolytes (SEs) with high Li-ion conductivities (sigma(ion)) and soft mechanical properties have limited applications in wet casting processes for commercial all-solid-state batteries (ASSBs) because of their inherent atmospheric and chemical instabilities. In this study, we fabricated sulfide SEs with a novel core-shell structure via environmental mechanical alloying, while providing sufficient control of the partial pressure of oxygen. This powder possesses notable atmospheric stability and chemical resistance because it is covered with a stable oxysulfide nanolayer that prevents deterioration of the bulk region. The core-shell SEs showed a sigma(ion) of more than 2.50 mS cm(-1) after air exposure (for 30 min) and reaction with slurry chemicals (mixing and drying for 31 min), which was approximately 82.8% of the initial sigma(ion). The ASSB cell fabricated through wet casting provided an initial discharge capacity of 125.6 mAh g(-1). The core-shell SEs thus exhibited improved powder stability and reliability in the presence of chemicals used in various wet casting processes for commercial ASSBs. English AMER CHEMICAL SOC IONIC-CONDUCTIVITY STABILITY SELECTION GLASSES Functionalized Sulfide Solid Electrolyte with Air-Stable and Chemical-Resistant Oxysulfide Nanolayer for All-Solid-State Batteries Article 10.1021/acsomega.0c03453 1 ACS OMEGA, v.5, no.40, pp.26015 - 26022 ACS OMEGA 5 40 26015 26022 scie scopus 000580943000055 2-s2.0-85094190183 Chemistry, Multidisciplinary Chemistry Article IONIC-CONDUCTIVITY STABILITY SELECTION GLASSES solid electrolyte sulfide environmental mechanical alloying core-shell structure all-solid-state battery