Kumar, Shalendra Sharma, Mayuri Aljawfi, Rezq Naji Chae, K. H. Kumar, Rajesh Dalela, Sourabh Alshoaibi, Adil Ahmed, Faheem Alvi, P. A. 2024-01-19T18:01:15Z 2024-01-19T18:01:15Z 2021-09-04 2020-04 0368-2048 https://pubs.kist.re.kr/handle/201004/118830 This paper presents the electronic structure and optical behavior of Sn1-xFexO2 (0 % <= x <= 7 %) nanoparticles synthesized using co-precipitation assisted hydrothermal method. The structural properties of as-synthesized nanoparticles were examined using XRD and Raman spectroscopy. The XRD results demonstrated that all the samples are crystallized in tetragonal (ruffle) crystal structure without any hint of impurity phase. The crystallite sizes measured using XRD spectra were found to vary from 7.0 to 10.0 nm. The effect of Fe doping and local defects were identified via surface-enhanced Raman spectroscopy (SEAS). The local electronic structure was studied using NEXAFS at Fe L-3,L- 2, O K edges which demonstrate that Fe ions are situated at the Sn sites with Fe3+ (pre-dominant) and Fe2+ (minor) mixed valance states. The octahedral (O-h) ligand field split the Fe (3d) state into t(2g) and e(g) states with similar to 3 eV energy splitting. The optical properties were explored by using UV-vis spectra, which reveals transparent behavior in the visible light region and good absorption in the ultraviolet range. The asymmetrical change in the bandgap energy (3.6-3.1 eV) with the variation in Fe dopant level may be due to the casual distribution of Fe ions inside the host SnO2 crystal texture. English ELSEVIER FERROMAGNETISM MAGNETORESISTANCE SURFACE RAMAN Tailoring the structural, electronic structure and optical properties of Fe: SnO2 nanoparticles Article 10.1016/j.elspec.2020.146934 1 JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, v.240 JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA 240 scie scopus 000528042300002 2-s2.0-85079200553 Spectroscopy Spectroscopy Article FERROMAGNETISM MAGNETORESISTANCE SURFACE RAMAN Fe doped SnO2 nanoparticles XRD Strain Raman spectra NEXAFS UV-vis-NIR spectroscopy