Nguyen, D.L.T. Kim, Y. Hwang, Y.J. Won, D.H. 2024-01-19T18:02:09Z 2024-01-19T18:02:09Z 2022-01-28 2020-03 2637-9368 https://pubs.kist.re.kr/handle/201004/118879 The conversion of carbon dioxide (CO2) to valuable fuels and chemicals offers a new pathway for sustainable and clean carbon fixation. Recently, the focus has been on electrochemical CO2 reduction on heterogeneous electrode catalysts, leading to remarkable achievements in the reaction performance. To date, CO2 to carbon monoxide (CO) conversion is considered as the most promising candidate reaction for the industrial market, owing to its high efficiency and reasonable technoeconomic feasibility. Moreover, CO has been proposed as a key intermediate species for further reduced hydrocarbons, which can pave the way for various fuel production. This study sets out to describe recent progress on the electrochemical CO2 reduction to CO in a heterogeneously catalyzed system. The review includes understanding of the catalytic material employed and engineering strategies implemented by adjusting the binding energy of key adsorbates. These material design approaches, such as nanostructuring, alloying, doping, and so forth, have pioneered breakouts in the intrinsic catalytic nature of transition metal elements. Moreover, recent advances in systematic design are summarized, with focus on practical industrial applications. Finally, perspectives on the design of electrocatalyst materials for CO production by electrochemical CO2 reduction are presented. ？ 2019 The Authors. Carbon Energy published by John Wiley & Sons Australia, Ltd on behalf of Wenzhou University. English Wiley Progress in development of electrocatalyst for CO2 conversion to selective CO production Article 10.1002/cey2.27 1 Carbon Energy, v.2, no.1, pp.72 - 98 Carbon Energy 2 1 72 98 Y scopus 000669744800005 2-s2.0-85106229979 Chemistry, Physical Energy & Fuels Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Energy & Fuels Science & Technology - Other Topics Materials Science Review N-DOPED CARBON ELECTROCHEMICAL REDUCTION EFFICIENT ELECTROREDUCTION ENHANCED CATALYTIC-ACTIVITY CARBON-DIOXIDE REDUCTION METAL-ELECTRODES HIGHLY EFFICIENT AQUEOUS CO2 GOLD NANOPARTICLES AU NANOPARTICLES CO production CO2 reduction reaction electrocatalyst