Kang, Dong Won Lee, Kyung Ah Kang, Minjung Kim, Jong Min Moon, Minkyu Choe, Jong Hyeak Kim, Hyojin Kim, Dae Won Kim, Jin Young Hong, Chang Seop 2024-01-19T18:31:55Z 2024-01-19T18:31:55Z 2021-09-04 2020-01 2050-7488 https://pubs.kist.re.kr/handle/201004/119161 For real-world applications of proton exchange membrane fuel cells (PEMFCs), potential electrolyte materials with high proton conductivity should possess activation energy as low as possible so that good conductivity can be achieved even at low operating temperatures. It is desirable and yet challenging to devise such materials with very low activation energy (<0.1 eV) while maintaining high conductivity. In this work, we have prepared phloroglucinol-based porous organic polymers (POPs) 1S1M, 1S2M, and 1S3Mvia post-synthetic impregnation of sulfuric acid into the pores. The superprotonic conductivity of 1S1M is 2.35 x 10(-1) S cm(-1) at 70 degrees C and 90% relative humidity (RH), with a significantly low activation energy of 0.075 eV. The conductivity exceeds that observed for POP-based conductors and is even superior to that of Nafion. Proton-conducting mixed matrix membranes (1S1MP, 1S2MP, and 1S3MP) composed of these powders and poly(vinylidene fluoride) have been fabricated via a drop casting method. 1S3MP exhibits a high proton conductivity of 2.13 x 10(-2) S cm(-1) at 80 degrees C and 90% RH. To the best of our knowledge, the activation energy (0.039 eV) of 1S3MP is the lowest recorded value among those for any proton conductive materials. The membrane, which is easy to fabricate and scalable for mass production, is durable over 3 weeks with invariant conductivity. English ROYAL SOC CHEMISTRY Cost-effective porous-organic-polymer-based electrolyte membranes with superprotonic conductivity and low activation energy Article 10.1039/c9ta06807d 1 JOURNAL OF MATERIALS CHEMISTRY A, v.8, no.3, pp.1147 - 1153 JOURNAL OF MATERIALS CHEMISTRY A 8 3 1147 1153 N scie scopus 000508855700021 2-s2.0-85078702940 Chemistry, Physical Energy & Fuels Materials Science, Multidisciplinary Chemistry Energy & Fuels Materials Science Article PROTON-EXCHANGE MEMBRANES SULFONIC-ACID GROUPS COMPOSITE MEMBRANES FUEL-CELLS FRAMEWORK CRYSTALLINE DEGRADATION POLYIMIDES CONDUCTORS TRANSPORT