Chae, Sang Youn Choi, Ja Youn Kim, Yoolim Nguyen, Dang Le Tri Joo, Oh-Shim 2024-01-19T19:00:15Z 2024-01-19T19:00:15Z 2021-09-04 2019-11-11 1433-7851 https://pubs.kist.re.kr/handle/201004/119335 Electrochemical and photoelectrochemical CO2 reductions were carried out with Re(bh-bipy)(CO)(3)(OH2) cocatalysts in aqueous electrolytes. Competition between hydrogen evolution and CO2 reduction was observed under (photo)electrochemical conditions for both glassy carbon and CuInS2 electrodes. The partial current density for CO generation is limited even though the additional potential is applied. However, electrochemical hydrogen evolution was suppressed under photoelectrochemical conditions, and the selectivity and partial current density for CO were considerably increased when compared to the electrochemical reduction in an identical electrode/electrolyte system. This finding may provide insights into using semiconductor/liquid junctions for solar fuel devices to overcome the limitations of electrolysis systems with an external bias. English John Wiley & Sons Ltd. PHOTOCATHODES COMPLEX WATER Photoelectrochemical CO2 Reduction with a Rhenium Organometallic Redox Mediator at Semiconductor/Aqueous Liquid Junction Interfaces Article 10.1002/anie.201908398 1 Angewandte Chemie International Edition, v.58, no.46, pp.16395 - 16399 Angewandte Chemie International Edition 58 46 16395 16399 scie scopus 000486807500001 2-s2.0-85073978602 Chemistry, Multidisciplinary Chemistry Article PHOTOCATHODES COMPLEX WATER carbon dioxide electrochemistry interfaces rhenium solar energy