Jai, Megha Manju Gundimeda, Abhiram Kumar, Akshay Kumar, Sanjay Gupta, Govind Won, Sung Ok Chae, Keun Hwa Vij, Ankush Thakur, Anup 2024-01-19T19:31:34Z 2024-01-19T19:31:34Z 2021-09-02 2019-08-15 0925-8388 https://pubs.kist.re.kr/handle/201004/119679 Fuel-blend combustion method using urea and monoethanolamine (MEA) fuels, is employed to tune the defect states and hence luminescence properties of nanocrystalline ZnAl2O4. Prepared nanocrystals flaunt a ravishing blue and intensified near-infrared (NIR) emission with varying intensities. Sample prepared using 80% MEA blended with 20% urea exhibits highest NIR emission, seven-fold intense than that prepared by 100% MEA, attributed to larger amount of deep band gap defects. Presence of multiple defects viz. vacancies of zinc, aluminium and oxygen is probed by means of Rietveld refinement, X-ray absorption near edge spectroscopy and photoluminescence spectroscopy. Band tailing and presence of shallow defect states are indicated by optical band gap and Urbach energy values. Broad range visible to NIR emission envisages application of ZnAl2O4 nanocrystals for bioimaging purposes. Radiative transitions among various defect levels contributing toward the emission have been depicted through a band model diagram. (C) 2019 Elsevier B.V. All rights reserved. English ELSEVIER SCIENCE SA OPTICAL-PROPERTIES GREEN SYNTHESIS ZNAL2O4 NANOPARTICLES NANOPHOSPHOR NANOPROBES MIXTURE XANES SIZE Enhanced near-infrared luminescence in zinc aluminate bestowed by fuel-blended combustion approach Article 10.1016/j.jallcom.2019.04.257 1 JOURNAL OF ALLOYS AND COMPOUNDS, v.797, pp.148 - 158 JOURNAL OF ALLOYS AND COMPOUNDS 797 148 158 scie scopus 000471128700018 2-s2.0-85065654127 Chemistry, Physical Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Chemistry Materials Science Metallurgy & Metallurgical Engineering Article OPTICAL-PROPERTIES GREEN SYNTHESIS ZNAL2O4 NANOPARTICLES NANOPHOSPHOR NANOPROBES MIXTURE XANES SIZE Rietveld refinement O K-edge Defects X-ray absorption spectroscopy Urbach energy Photoluminescence