Lee, Sechan Hong, Jihyun Jung, Sung-Kyun Ku, Kyojin Kwon, Giyun Seong, Won Mo Kim, Hyungsub Yoon, Gabin Kang, Inyeong Hong, Kootak Jang, Ho Won Kang, Kisuk 2024-01-19T20:00:13Z 2024-01-19T20:00:13Z 2021-09-02 2019-07 2405-8297 https://pubs.kist.re.kr/handle/201004/119862 Organic redox compounds are potential substitutes for transition-metal-oxide electrode materials in rechargeable batteries because of their low cost, minimal environmental footprint, and chemical diversity. However, their inherently low electrical conductivity and high solubility in organic solvents are serious impediments to achieving performance comparable to that of currently used inorganic-based electrode materials. Herein, we report organic charge-transfer complexes as a novel class of electrode materials with intrinsically high electrical conductivity and low solubility that can potentially overcome the chronic drawbacks associated with organic electrodes. The formation of the charge-transfer complexes, phenazine-7,7,8,8-tetracyanoquinodimethane and dibenzo-1,4-dioxin-7,7,8,8-tetracyanoquinodimethane, via a room-temperature process leads to enhancement in the electrical conductivity and reduction in the dissolution resulting in the high power and cycle performances that far outperform those of each single-moiety counterpart. This finding demonstrates the general applicability of the charge-transfer complex to simultaneously improve the electrical conductivity and mitigate the shortcomings of existing single-moiety-based organic electrode materials, and opens up an uncharted pathway toward the development of high-performance organic electrode materials via the exploration of various combinations of donor-acceptor monomers with different stoichiometry. English Elsevier BV Charge-transfer complexes for high-power organic rechargeable batteries Article 10.1016/j.ensm.2019.05.001 1 Energy Storage Materials, v.20, pp.462 - 469 Energy Storage Materials 20 462 469 N scie scopus 000472961700044 2-s2.0-85066074718 Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Science & Technology - Other Topics Materials Science Article LITHIUM-ION BATTERIES ELECTRODE MATERIALS PACKING ARRANGEMENT MOLECULAR-COMPOUNDS STORAGE DERIVATIVES TRANSITION TRANSPORT ACCEPTOR POLYMER Organic rechargeable batteries Charge-transfer complex High power organic electrodes Donor-acceptor complex Novel organic electrode material candidates