Gunasekar, Gunniya Hariyanandam Kim, Honggon Yoon, Sungho 2024-01-19T20:30:26Z 2024-01-19T20:30:26Z 2021-09-02 2019-04-01 2398-4902 https://pubs.kist.re.kr/handle/201004/120126 In this study, catalytic dehydrogenation of formic acid into H-2/CO2 using half-sandwich Rh(iii)/Ir(iii) catalysts immobilized on variable dimensions of bipyridine-based covalent triazine frameworks (bpy-CTFs) has been described for the first time with a highest initial turnover frequency of 7930 h(-1). A systematic study on the influence of the central metal cation (Rh vs. Ir), CTF architectures and amount of metal loadings on the CTF is presented. English ROYAL SOC CHEMISTRY HYDROGEN GENERATION ROOM-TEMPERATURE CO2 FUTURE DECOMPOSITION COMPLEX Dehydrogenation of formic acid using molecular Rh and Ir catalysts immobilized on bipyridine-based covalent triazine frameworks Article 10.1039/c9se00002j 1 SUSTAINABLE ENERGY & FUELS, v.3, no.4, pp.1042 - 1047 SUSTAINABLE ENERGY & FUELS 3 4 1042 1047 scie scopus 000467219500013 2-s2.0-85063434976 Chemistry, Physical Energy & Fuels Materials Science, Multidisciplinary Chemistry Energy & Fuels Materials Science Article HYDROGEN GENERATION ROOM-TEMPERATURE CO2 FUTURE DECOMPOSITION COMPLEX formic acid dehydrogenation Rh catalyst Ir catalyst triazine framework