Yi, Seung Yeop Song, Young Geun Park, Jae Yeol Suh, Jun Min Kim, Gwang Su Shim, Young-Seok Yuk, Jong Min Kim, Sangtae Jang, Ho Won Ju, Byeong-Kwon Kang, Chong-Yun 2024-01-19T20:34:16Z 2024-01-19T20:34:16Z 2021-09-02 2019-02-20 1944-8244 https://pubs.kist.re.kr/handle/201004/120338 Morphological evolution accompanying a surface roughening and preferred orientation is an effective way to realize a high-performance gas sensor because of its significant potential as a chemical catalyst through chemical potentials and atomic energy states. In this work, we investigated a heterojunction of double-side-W-decorated NiO nanoigloos fabricated through radio frequency sputtering and a soft-template method. Interestingly, a morphological evolution characterized by a pyramidal rough surface and the preferred orientation of the (111) plane was observed upon decorating the bare NiO nanoigloos with W. The underlying mechanism of the morphological evolution was precisely demonstrated based on the van der Drift competitive growth model originating from the oxygen transport and chemical strain in the lattice. The gas sensing properties of W-decorated NiO show an excellent NO2 response and selectivity when compared to other gases. In addition, high response stability was evaluated under interference gas and humidity conditions. The synergistic effects on the sensing performance were interpreted on the basis of the morphological evolution of W-decorated NiO nanoigloos. English American Chemical Society NO2 FILMS NANOSTRUCTURES GROWTH SIZE ZNO NANOPARTICLES SELECTIVITY FABRICATION NANOSHEETS Morphological Evolution Induced through a Heterojunction of W-Decorated NiO Nanoigloos: Synergistic Effect on High-Performance Gas Sensors Article 10.1021/acsami.8b18678 1 ACS Applied Materials & Interfaces, v.11, no.7, pp.7529 - 7538 ACS Applied Materials & Interfaces 11 7 7529 7538 scie scopus 000459642200091 2-s2.0-85061544490 Nanoscience & Nanotechnology Materials Science, Multidisciplinary Science & Technology - Other Topics Materials Science Article NO2 FILMS NANOSTRUCTURES GROWTH SIZE ZNO NANOPARTICLES SELECTIVITY FABRICATION NANOSHEETS nanostructure heterojunction morphological evolution gas sensor NO2