Han, Seo-Jung Bhat, Vikram Stoltz, Brian M. Virgil, Scott C. 2024-01-19T21:01:28Z 2024-01-19T21:01:28Z 2021-09-02 2019-02 1615-4150 https://pubs.kist.re.kr/handle/201004/120429 The atroposelective synthesis of PINAP ligands has been accomplished via a palladium-catalyzed C-P coupling process through dynamic kinetic asymmetric transformation. These catalytic conditions allow access to a wide variety of alkoxy- and benzyloxy-substituted PINAP ligands in high enantiomeric excess. The methods described in this communication afford valuable P,N ligands in good yields and high enantioselectivity using low catalyst loading. English John Wiley & Sons Ltd. Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation Article 10.1002/adsc.201801248 1 Advanced Synthesis and Catalysis, v.361, no.3, pp.441 - 444 Advanced Synthesis and Catalysis 361 3 441 444 N scie scopus 000457795500006 2-s2.0-85058110101 Chemistry, Applied Chemistry, Organic Chemistry Article CATALYZED ENANTIOSELECTIVE DIBORATION TERMINAL ALKYNES QUINAP HYDROBORATION RESOLUTION LIGANDS BIARYLS PINAP Dynamic kinetic asymmetric transformation Atroposelective synthesis P,N ligands