Lim, Minkyung Kim, Hyeji Ban, Jaeyoung Son, Junghan Lee, Jae Kyun Min, Sun-Joon Lee, Sang Uck Rhee, Hakjune 2024-01-19T21:31:05Z 2024-01-19T21:31:05Z 2021-09-04 2018-11-08 1434-193X https://pubs.kist.re.kr/handle/201004/120690 Palladium-catalyzed carbonylative coupling reactions of various N,N-bis(methanesulfonyl)amides with arylboronic acids through C-N bond cleavage were carried out. The reactions proceeded under mild conditions in a short period of time without any additives to afford a wide range of unsymmetrical aryl ketones in excellent yields. This is the first example of a carbonylative coupling reaction using N,N-bis(methanesulfonyl)amide as a coupling substrate. English WILEY-V C H VERLAG GMBH FRIEDEL-CRAFTS ACYLATION ELECTRONICALLY-ACTIVATED AMIDES ACYL-TRANSFER REAGENTS SUZUKI-MIYAURA ARYLBORONIC ACIDS CARBOXYLIC ANHYDRIDES KETONE SYNTHESIS DIARYL KETONES IONIC LIQUIDS ARYL BROMIDES Palladium-Catalyzed Carbonylative Coupling Reactions of N,N-Bis(methanesulfonyl)amides through C-N Bond Cleavage Article 10.1002/ejoc.201801124 1 EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2018, no.41, pp.5717 - 5724 EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 2018 41 5717 5724 scie scopus 000449649100012 2-s2.0-85053794422 Chemistry, Organic Chemistry Article FRIEDEL-CRAFTS ACYLATION ELECTRONICALLY-ACTIVATED AMIDES ACYL-TRANSFER REAGENTS SUZUKI-MIYAURA ARYLBORONIC ACIDS CARBOXYLIC ANHYDRIDES KETONE SYNTHESIS DIARYL KETONES IONIC LIQUIDS ARYL BROMIDES Synthetic methods Palladium C-N bond cleavage Amides Cross-coupling