Feng, Jingchun Xie, Weijie Liu, Xiaoming Tang, Xinghua Yan, Liushui Guo, Huiqin Al Kheraif, Abdulaziz A. Jang, Ho Seong Lin, Jun 2024-01-19T21:31:35Z 2024-01-19T21:31:35Z 2022-01-25 2018-11 0022-2313 https://pubs.kist.re.kr/handle/201004/120717 Here, we demonstrate a new recreating blue-purple luminescence of La2Zr3(MoO4)(9) and host sensitized luminescence in La2Zr3(MoO4)(9): Ln(3+) (Ln(3+) = Dy3+ and/or Eu3+) nanocrystalline phosphors with multi-color luminescence evolution in response to UV light excitation. A series of La2Zr3(MoO4)(9) and La2Zr3(MoO4)(9): Ln(3+) (Ln(3+) = Dy3+ and/or Eu3+) nanocrystalline phosphors were synthesized via a citrate sol-gel method. X-ray diffractometer, FE-SEM, HRTEM, diffuse reflection spectra, photoluminescence spectra, and fluorescent decay lifetimes were utilized to characterize the prepared phosphors. The XRD results reveal that the prepared La2Zr3(MoO4)(9) and La2Zr3(MoO4)(9): Ln(3+) (Ln(3+) = Dy3+ and/or Eu3+) nanocrystalline phosphors present a single-phased trigonal crystal structure. FE-SEM and HRTEM images indicate that the prepared La2Zr3(MoO4)(9): Ln(3+) phosphors consist of fine and spherical grains in size of around 35-60 nm in diameter. Under the excitation of ultraviolet light, the La2Zr3(MoO4)(9) presents a characteristic broad band emission of MoO4 group from 300 to 550 nm peaking at 399 nm, and the La2Zr3(MoO4)(9): Ln(3+) (Ln(3+)= Dy3+ and/or Eu3+) phosphors show the characteristic emissions of Dy3+ (F-4(9/2) -> H-6(15/2) and F-4(9/2) -> H-6(13/2) transitions) and Eu3+ (D-5(0) -> F-7(J) transitions, J = 1, 2, 3, and 4), respectively. There exists an energy transfer from La2Zr3(MoO4)(9) host lattice to Dy3+ and Eu3+ ions in La2Zr3(MoO4)(9): Ln(3+) (Ln(3+) = Dy3+ and/or Eu3+) phosphor. The luminescence color of La2Zr3(MoO4)(9): Ln(3+) (Ln(3+) = Dy3+ and/or Eu3+) can be tuned from blue-white, white to orange-red by adjusting the doping concentration and the relative ratio of Dy3+ to Eu3+ in La2Zr3(MoO4)(9) host lattice. A single-phase white-light-luminescence with high color purity has been realized in La2Zr3(MoO4)(9): Dy3+, Eu3+ phosphor. The obtained La2Zr3(MoO4)(9): Dy3+, Eu3+ phosphor has potential application in area of UV-pumped white light-emitting devices. English ELSEVIER Multi-color luminescence evolution of La2Zr3(MoO4)(9): Ln(3+) (Ln(3+) = Dy3+ and/or Eu3+) nanocrystalline phosphors for UV-pumped white light-emitting devices Article 10.1016/j.jlumin.2018.06.032 1 JOURNAL OF LUMINESCENCE, v.203, pp.179 - 188 JOURNAL OF LUMINESCENCE 203 179 188 N scie scopus 000440665500024 2-s2.0-85048933004 Optics Optics Article HOST-SENSITIZED LUMINESCENCE COLOR-TUNABLE LUMINESCENCE ENERGY-TRANSFER PROPERTIES PHOTOLUMINESCENCE PROPERTIES OPTICAL-PROPERTIES EMISSION ENHANCEMENT MOLYBDATE IONS RE La2Zr3(MoO4)(9) Nanocrystalline phosphors Light-emitting diodes