Feizi, Hadi Shiri, Farshad Bagheri, Robabeh Singh, Jitendra Pal Chae, Keun Hwa Song, Zhenlun Najafpour, Mohammad Mahdi 2024-01-19T22:02:56Z 2024-01-19T22:02:56Z 2021-09-03 2018-08-07 2044-4753 https://pubs.kist.re.kr/handle/201004/121045 Herein, the role of Ni oxide in the electrocatalytic water oxidation of a nickel (II) Schiff base (N,N'-bis (salicylidene) ethylenediamino nickel (II)) is investigated using scanning electron microscopy, transmission electron microscopy, energy dispersive spectrometry, X-ray diffraction, nuclear magnetic resonance spectroscopy, extended X-ray absorption fine structure, X-ray absorption near edge structure, chronoamperometry, electrochemical methods and theoretical calculations. Although Ni oxide does not have a pure, simple and crystalline structure, the experiments showed that Ni oxide at a pH of 11 is a water-oxidizing catalyst on the surface of a fluorine-doped tin oxide electrode. At pH 3 or 7, no clear water oxidation or NiOx formation was detected. Below this low pH, a solid with high carbon content was detected, which is not a water-oxidizing catalyst. A metal oxide-based mechanism for water oxidation in the presence of a metal complex has not been considered using theoretical calculations. Herein, our theoretical calculations indicated that after the oxidation of the Ni (II) complex, all Ni equatorial bonds in the oxidation state of III were weakened. This effect may cause the decomposition of the intermediate to NiOx. This study could be very promising for the design and synthesis of new, efficient and stable catalysts. English ROYAL SOC CHEMISTRY MANGANESE OXIDE ELECTROCHEMICAL IMPEDANCE ARTIFICIAL PHOTOSYNTHESIS HETEROGENEOUS CATALYSIS OXIDIZING CATALYST IRIDIUM COMPLEXES MOLECULAR-SYSTEMS PHOTOSYSTEM-II NEUTRAL PH EFFICIENT The application of a nickel(II) Schiff base complex in water oxidation: the importance of nanosized materials Article 10.1039/c8cy00582f 1 CATALYSIS SCIENCE & TECHNOLOGY, v.8, no.15, pp.3954 - 3968 CATALYSIS SCIENCE & TECHNOLOGY 8 15 3954 3968 scie scopus 000445750100026 2-s2.0-85051091197 Chemistry, Physical Chemistry Article MANGANESE OXIDE ELECTROCHEMICAL IMPEDANCE ARTIFICIAL PHOTOSYNTHESIS HETEROGENEOUS CATALYSIS OXIDIZING CATALYST IRIDIUM COMPLEXES MOLECULAR-SYSTEMS PHOTOSYSTEM-II NEUTRAL PH EFFICIENT nickelIJII) Schiff base complex water oxidation nanosized materials extended X-ray absorption fine structure