Cho, Kie Yong Kim, Hyun-Ji Do, Xuan Huy Seo, Jin Young Choi, Jae-Woo Lee, Sang-Hyup Yoon, Ho Gyu Hwang, Seung Sang Baek, Kyung-Youl 2024-01-19T22:03:47Z 2024-01-19T22:03:47Z 2021-09-03 2018-08 0922-6168 https://pubs.kist.re.kr/handle/201004/121090 Two series of water-soluble metalloporphyrin-cored amphiphilic star block copolymers were synthesized by controlled radical polymerizations such as atom transfer radical polymerization (ATRP) and reversible addition fragmentation chain transfer (RAFT), which gave eight amphiphilic block copolymer arm chains consisting of poly(n-butyl acrylate-b-poly(ethylene glycol) methyl ether methacylate) (PnBA-b-PEGMEMA, M-n,M-GPC = 78,000, M-w/M-n = 1.2, 70 wt% of PPEGMEMA) and poly(styrene-b-2-dimethylamino ethyl acrylate) (PS-b-PDMAEA, M-n,M-GPC = 83,000, M-w/M-n = 1.2, 67 wt% of PDMAEA), yielding porphyrin(Pd)-(PnBA-b-PPEGMEMA)(8) and porphyrin(Pd)-(PS-b-PDMAEA)(8), respectively. Obtained metalloporphyrin polymer photocatalysts were homogeneously solubilized in water to apply to the removal of chlorophenols in water, and was distinguished from conventional water-insoluble small molecular metalloporphyrin photocatalysts. Notably, we found that the water-soluble star block copolymers with hydrophobic-hydrophilic core-shell structures more effectively decomposed the chlorophenol, 2,4,6-trichlorophenol (2,4,6-TCP), in water under visible light irradiation (k = 1.39 h(-1), t(1/2) = 0.5 h) in comparison to the corresponding water-soluble star homopolymer, because the hydrophobic core near the metalloporphyrin effectively captured and decomposed the hydrophobic chlorophenols in water. English SPRINGER Synthesis of water soluble metalloporphyrin-cored amphiphilic star block copolymer photocatalysts for an environmental application Article 10.1007/s11164-018-3272-9 1 RESEARCH ON CHEMICAL INTERMEDIATES, v.44, no.8, pp.4663 - 4684 RESEARCH ON CHEMICAL INTERMEDIATES 44 8 4663 4684 N scie scopus 000439954400008 2-s2.0-85042180332 Chemistry, Multidisciplinary Chemistry Article RADICAL POLYMERIZATION CATALYTIC-OXIDATION DEGRADATION NANOPARTICLES GRAPHENE 2,4-DICHLOROPHENOL DECHLORINATION 2-CHLOROPHENOL CHLOROPHENOLS REDUCTION Metalloporphyrins Amphiphilic star block copolymers Living radical polymerizations Photocatalysis Chlorophenols