Juarez, Xitlali G. Ko, Hyungduk Jang, Ho Seong 2024-01-19T22:04:00Z 2024-01-19T22:04:00Z 2021-09-03 2018-08 0922-6168 https://pubs.kist.re.kr/handle/201004/121102 Efficient upconversion (UC)-downshifting (DS), dual-mode-emitting NaGdF4:Yb,Tm/NaGdF4:Tb/NaYF4 core/shell/shell (C/S/S) nanophosphors (NPs) were synthesized. The UC luminescence color changed from blue to sky blue after doping Tb3+ into NaGdF4 shell because Tb3+ emission peaks via D-5(4) -> F-7(J) transition were observed with Tm3+ emission peaks via D-1(2) -> F-3(4) and (1)G(4) -> H-3(6) transitions through the energy migration UC process of Yb3+ -> Tm3+ -> Gd3+ -> Tb3+. Upon increasing the Tb3+ concentration in the NaGdF4 shell from 5 to 15%, the Commission Internationale de l'Aeclairage (CIE) color coordinates changed from (0.2188, 0.2390) to (0.2616, 0.3654). When NaGdF4:Yb(49%),Tm(1%)/NaGdF4:Tb(15%)/NaYF4 NPs were excited using 273 nm ultraviolet light, the C/S/S NPs exhibited bright green light with CIE color coordinates of (0.3354, 0.5090) as a result of energy transfer from Gd3+ to Tb3+. These bright UC-DS, dual-mode-emitting C/S/S NPs could be applied in various applications, including multiplexed imaging and anticounterfeiting. English SPRINGER ENERGY MIGRATION SHELL NANOPARTICLES POLYMER COMPOSITES NAYF4 NANOCRYSTALS Strong upconversion-downshifting green emission from Tb3+ ions in core/shell/shell-structured nanophosphors Article 10.1007/s11164-018-3276-5 1 RESEARCH ON CHEMICAL INTERMEDIATES, v.44, no.8, pp.4641 - 4650 RESEARCH ON CHEMICAL INTERMEDIATES 44 8 4641 4650 scie scopus 000439954400006 2-s2.0-85040863075 Chemistry, Multidisciplinary Chemistry Article ENERGY MIGRATION SHELL NANOPARTICLES POLYMER COMPOSITES NAYF4 NANOCRYSTALS Upconversion Downshifting Core/shell/shell Nanophosphor Energy migration