Lee, Heejin Lee, Jae Kyun Min, Sun-Joon Seo, Hyeonglim Lee, Youngbok Rhee, Hakjune 2024-01-19T23:01:31Z 2024-01-19T23:01:31Z 2021-09-03 2018-04-20 0022-3263 https://pubs.kist.re.kr/handle/201004/121465 The copper(I)-catalyzed azide-alkyne cycloaddition reaction has been extensively studied and widely applied in organic synthesis. However, the formation of 1,2,3-triazoles with electron-deficient azide has been a challenging problem. In this report, we have demonstrated the formation of regioselective 1,4-disubstituted 1,2,3-triazoles from various types of aryl terminal alkynes and azidoformates, which are electron-deficient azides, using a commercialized [Cu-(CH3CN)(4)]PF6 copper(I) catalyst under mild conditions. English AMER CHEMICAL SOC ONE-POT SYNTHESIS CLICK CHEMISTRY ROOM-TEMPERATURE SULFONYL AZIDES ANTI-3-ARYL-2,3-DIBROMOPROPANOIC ACIDS MEDICINAL CHEMISTRY ORGANIC AZIDES SODIUM-AZIDE SOLID-PHASE CYCLOADDITION Copper(I)-Catalyzed Synthesis of 1,4-Disubstituted 1,2,3-Triazoles from Azidoformates and Aryl Terminal Alkynes Article 10.1021/acs.joc.8b00022 1 JOURNAL OF ORGANIC CHEMISTRY, v.83, no.8, pp.4805 - 4811 JOURNAL OF ORGANIC CHEMISTRY 83 8 4805 4811 scie scopus 000430898500048 2-s2.0-85045744146 Chemistry, Organic Chemistry Article ONE-POT SYNTHESIS CLICK CHEMISTRY ROOM-TEMPERATURE SULFONYL AZIDES ANTI-3-ARYL-2,3-DIBROMOPROPANOIC ACIDS MEDICINAL CHEMISTRY ORGANIC AZIDES SODIUM-AZIDE SOLID-PHASE CYCLOADDITION N-Sulfonyl triazoles Phenyl Azidoformate 1,4-disubstituted 1,2,3-triazoles