Heo, Jin Hyuck Park, Sungmin Im, Sang Hyuk Son, Hae Jung 2024-01-20T00:03:18Z 2024-01-20T00:03:18Z 2021-09-03 2017-11-15 1944-8244 https://pubs.kist.re.kr/handle/201004/122061 In perovskite solar cells (PSCs), overlying hole transporting materials (HTMs) are important for achieving high efficiencies as well as protecting perovskite active layers from degradation factors. This study reports the synthesis of a dopant-free HTM based on a D'-A-D-A-D-A-D' (D, D': electron donor, A: electron acceptor) conjugated structure and incorporation of the HTM into a PSC. The resulting PSC exhibits a high efficiency of 17.3%, which is comparable to that of the device based on doped spiro-OMeTAD HTM, and exhibits much improved stability: without encapsulation, the PSC based on the new HTM was found to retain 80% of its initial performance over 500 h under the conditions of 60% relative humidity/1 sun light-soaking without encapsulation. The high performance is attributed to efficient hole-extraction/collection and hole transport. We demonstrate that the extended pi-structure of the D'-A-D-A-D-A-D'-type HTM slows moisture intrusion and protects the perovskite layer better than smaller D-A-type molecules. The improved stability is primarily due to the hydrophobic nature of the HTM; the relatively large pi-conjugated molecule forms denser films, which effectively decrease the spaces between the molecules and retard water intrusion. The dopant-free D-A-type HTM with an extended pi-structure is effective not only in improving device efficiency, but also device stability. English American Chemical Society HIGH FILL FACTORS PHOTOVOLTAIC EFFICIENCY CHARGE-TRANSPORT STATE LENGTHS Development of Dopant-Free Donor-Acceptor-type Hole Transporting Material for Highly Efficient and Stable Perovskite Solar Cells Article 10.1021/acsami.7b11938 1 ACS Applied Materials & Interfaces, v.9, no.45, pp.39511 - 39518 ACS Applied Materials & Interfaces 9 45 39511 39518 scie scopus 000416203800043 2-s2.0-85034636133 Nanoscience & Nanotechnology Materials Science, Multidisciplinary Science & Technology - Other Topics Materials Science Article HIGH FILL FACTORS PHOTOVOLTAIC EFFICIENCY CHARGE-TRANSPORT STATE LENGTHS dopant-free hole transporting material perovskite solar cells power conversion efficiency solar cell stability