Yoo, Kwang Soo Kang, Yeon Hui Im, Kyoung Ran Kim, Chang-Sam 2024-01-20T00:04:32Z 2024-01-20T00:04:32Z 2021-09-03 2017-11 1996-1944 https://pubs.kist.re.kr/handle/201004/122130 Al2O3-coated Li(Ni0.6Co0.2Mn0.2)O-2 cathode materials were prepared by simple surface modification in water media through a sol-gel process with a dispersant. The crystallinity and surface morphology of the samples were characterized through X-ray diffraction analysis and scanning electron microscopy observation. The Li(Ni0.6Co0.2Mn0.2)O-2 cathode material was of a polycrystalline hexagonal structure and agglomerated with particles of approximately 0.3 to 0.8 m in diameter. The nanosized Al2O3 particles of low concentration (0.06-0.12 wt %) were uniformly coated on the surface of Li(Ni0.6Co0.2Mn0.2)O-2. Measurement of electrochemical properties showed that Li(Ni0.6Co0.2Mn0.2)O-2 coated with Al2O3 of 0.08 wt % had a high initial discharge capacity of 206.9 mAh/g at a rate of 0.05 C over 3.0-4.5 V and high capacity retention of 94.5% at 0.5 C after 30 cycles (cf. uncoated sample: 206.1 mAh/g and 90.8%, respectively). The rate capability of this material was also improved, i.e., it showed a high discharge capacity of 166.3 mAh/g after 5 cycles at a rate of 2 C, whereas the uncoated sample showed 155.8 mAh/g under the same experimental conditions. English MDPI RECENT PROGRESS LINI0.6CO0.2MN0.2O2 RICH LICOO2 VOLTAGE Surface Modification of Li(Ni0.6Co0.2Mn0.2)O-2 Cathode Materials by Nano-Al2O3 to Improve Electrochemical Performance in Lithium-Ion Batteries Article 10.3390/ma10111273 1 MATERIALS, v.10, no.11 MATERIALS 10 11 scie scopus 000416786200051 2-s2.0-85033372462 Chemistry, Physical Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Physics, Applied Physics, Condensed Matter Chemistry Materials Science Metallurgy & Metallurgical Engineering Physics Article RECENT PROGRESS LINI0.6CO0.2MN0.2O2 RICH LICOO2 VOLTAGE lithium-ion batteries Ni-rich cathode materials nano-Al2O3 coating surface modification electrochemical property