Kim, Haeri Park, Hyun Seo Hwang, Yun Jeong Min, Byoung Koun 2024-01-20T00:30:20Z 2024-01-20T00:30:20Z 2021-09-03 2017-10-19 1932-7447 https://pubs.kist.re.kr/handle/201004/122154 The electrocatalytic property of a flat or an oxide-derived nanostructure Au electrode was investigated using surface sensitive analysis methods such as impedance spectroscopy and Kelvin probe force microscopy (KPFM) when electrochemical conversion of carbon dioxide (CO2) to carbon monoxide (CO) was performed with either KHCO3- or NaHCO3-based neutral electrolyte. A strong dependence on the cation of the electrolyte was exhibited on the flat Au electrode surface. CO selectivity and capacitance dispersion are significantly higher with the KHCO3 electrolyte. On the other hand, the nanostructured Au electrodes, having much more improved activity and durability of CO2 reduction, showed much less electrolyte-dependent catalytic activity. The difference in CO selectivity with KHCO3 and NaHCO3 electrolytes can be explained by the difference in hydration level and consequent adsorption strength of the cations on the flat Au metal electrodes, implying that ion-pairing interactions between the metal, cations, CO2, and its intermediate play an important role in the reduction reaction. The local electric field fluctuation caused by the nanostructured rough Au surface can affect the electric double layer near the electrode surface and suppress the electrolyte-dependency of the reduction. Furthermore, according to X-ray spectroscopy analysis of the electrode after electrolysis, the nanostructured Au electrode is less prone to surface cation deposition. These results provide a basic understanding of the role of electrolyte cations in the CO2 reduction reaction. English American Chemical Society CARBON-DIOXIDE REDUCTION DOUBLE-LAYER CAPACITANCE ELECTROREDUCTION ACTIVITY RENEWABLE ENERGY ANION-ADSORPTION ELECTROCATALYST INTERFACE IMPEDANCE SELECTIVITY ACTIVATION Surface-Morphology-Dependent Electrolyte Effects on Gold-Catalyzed Electrochemical CO2 Reduction Article 10.1021/acs.jpcc.7b06286 1 The Journal of Physical Chemistry C, v.121, no.41, pp.22637 - 22643 The Journal of Physical Chemistry C 121 41 22637 22643 scie scopus 000413617900006 2-s2.0-85031945757 Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Science & Technology - Other Topics Materials Science Article CARBON-DIOXIDE REDUCTION DOUBLE-LAYER CAPACITANCE ELECTROREDUCTION ACTIVITY RENEWABLE ENERGY ANION-ADSORPTION ELECTROCATALYST INTERFACE IMPEDANCE SELECTIVITY ACTIVATION gold CO2 reduction electrolyte