Na, Wonjun Lee, Albert S. Lee, Jin Hong Hong, Soon Man Kim, Eunkyoung Koo, Chong Min 2024-01-20T00:30:29Z 2024-01-20T00:30:29Z 2022-01-10 2017-10-15 0167-2738 https://pubs.kist.re.kr/handle/201004/122163 Thermally curable hybrid ionogel electrolytes consisting of epoxy-functionalized POSS, amine-terminated polypropylene glycol, and ionic liquid electrolyte, 1 M LiTFSI in BMPTFSI were fabricated to give ionic conducting epoxy networks with cubic inorganic star networks crosslinked with lithium ion dissociating polypropylene glycol linkers. Characterization of these hybrid ionogels revealed high ion conduction, exceptional thermal stability, and electrochemical stability. Lithium ion capacitors fabricated with these hybrid ionogels revealed exceptional performance on par with the neat liquid ionic liquid electrolyte, and far superior over ionogels fabricated with conventional organic crosslinkers, due to the mechanical robustness and lithium ion dissociative character imparted by the POSS and PPG functionalities. English ELSEVIER SCIENCE BV CHEMICAL CROSS-LINKING POLYMER ELECTROLYTES POLY(ETHYLENE OXIDE) POLYETHYLENE OXIDE BATTERIES BEHAVIOR LIQUIDS Hybrid ionogel electrolytes with POSS epoxy networks for high temperature lithium ion capacitors Article 10.1016/j.ssi.2017.06.017 1 SOLID STATE IONICS, v.309, pp.27 - 32 SOLID STATE IONICS 309 27 32 scie scopus 000412266100005 2-s2.0-85021744121 Chemistry, Physical Physics, Condensed Matter Chemistry Physics Article CHEMICAL CROSS-LINKING POLYMER ELECTROLYTES POLY(ETHYLENE OXIDE) POLYETHYLENE OXIDE BATTERIES BEHAVIOR LIQUIDS Polyhedral oligomeric silsesquioxanes Ionogel Lithium ion capacitor Epoxy