Jang, Yoon Hee Lee, Jang Mi Seo, Jung Woo Kim, Inho Lee, Doh-Kwon 2024-01-20T00:32:21Z 2024-01-20T00:32:21Z 2021-09-05 2017-09-28 2050-7488 https://pubs.kist.re.kr/handle/201004/122262 We demonstrate semi-transparent inverted planar perovskite solar cells (PSCs) for monolithic tandem construction with an electrodeposited CuInSe2 (CISe) solar cell. To eliminate the severe degradation of perovskite/PCBM layers during a transparent conducting oxide sputtering process, a thin ZnO nanoparticle (NP) layer is introduced onto the electron-extracting PCBM layer by a simple solution process without a post-annealing step. It is found that a thin ZnO-NP layer with an optimal thickness facilitates the electron transfer from PCBM to the Ag back contact in opaque devices while also helping to protect the underlying layers from plasma-induced damage in semi-transparent devices. As a result, semi-transparent PSC devices with an inverted architecture having a sputtered Al-doped ZnO top electrode are realized with power conversion efficiencies over 10%. In addition, monolithically integrated, two-terminal tandem devices composed of solution-processed CISe/perovskite are successfully fabricated, demonstrating an efficiency of 11% with a negligible degree of hysteresis. English ROYAL SOC CHEMISTRY ORGANOMETAL HALIDE PEROVSKITE PHOTOVOLTAIC PERFORMANCE EFFICIENT RECOMBINATION Monolithic tandem solar cells comprising electrodeposited CuInSe2 and perovskite solar cells with a nanoparticulate ZnO buffer layer Article 10.1039/c7ta06163c 1 JOURNAL OF MATERIALS CHEMISTRY A, v.5, no.36, pp.19439 - 19446 JOURNAL OF MATERIALS CHEMISTRY A 5 36 19439 19446 scie scopus 000411232100059 2-s2.0-85029653417 Chemistry, Physical Energy & Fuels Materials Science, Multidisciplinary Chemistry Energy & Fuels Materials Science Article ORGANOMETAL HALIDE PEROVSKITE PHOTOVOLTAIC PERFORMANCE EFFICIENT RECOMBINATION tandem monolithic CIGS perovskite