Kim, Min June Lee, Kang-Bong Seo, Myung-gi Lee, Kwan-Young 2024-01-20T01:01:41Z 2024-01-20T01:01:41Z 2021-09-05 2017-08 0256-1115 https://pubs.kist.re.kr/handle/201004/122473 H2O2 vapor sterilization is an effective and safe method for removing various pathogens. To improve the efficiency of this technique, the time required for sterilization must be shortened. The aeration time constitutes a large portion of the total sterilization time; therefore, the development of a catalyst for H2O2 decomposition is necessary. Bulk MnO2 is typically used in H2O2 decomposition, but it has a low specific surface area. To increase H2O2 decomposition activity, specific surface area and electron transfer ability of catalyst need improvement. In this study, MnO2/CNT(x), where x denotes the weight ratio of CTAB to H2O in the catalyst preparation, was synthesized using a soft template method with varying amounts of the template. Overall, the catalyst specific surface area remarkably increased to 190-200 m(2)/g from 0.043 m(2)/g for bulk MnO2 and these increased surface areas resulted in superior H2O2 decomposition activity. Among the CNT-supported catalysts tested, MnO2/CNT (1.0) exhibited the highest activity, which was 570 times that of bulk MnO2. Aeration times were also calculated with some assumptions and the aeration can be finished within 1 hr (bulk MnO2 needs about 25 hr). English KOREAN INSTITUTE CHEMICAL ENGINEERS ETHYLENE-OXIDE STERILIZATION OXYGEN MECHANISM GAS Porous MnO2/CNT catalysts with a large specific surface area for the decomposition of hydrogen peroxide Article 10.1007/s11814-017-0120-3 1 KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.34, no.8, pp.2147 - 2153 KOREAN JOURNAL OF CHEMICAL ENGINEERING 34 8 2147 2153 scie scopus kci ART002248389 000406393800003 2-s2.0-85021070181 Chemistry, Multidisciplinary Engineering, Chemical Chemistry Engineering Article ETHYLENE-OXIDE STERILIZATION OXYGEN MECHANISM GAS Manganese Oxide Catalyst Soft Template Method Large Surface Area Hydrogen Peroxide Decomposition Aeration