Lee, Jin Hong Lee, Albert S. Lee, Jong-Chan Hong, Soon Man Hwang, Seung Sang Koo, Chong Min 2024-01-20T02:04:09Z 2024-01-20T02:04:09Z 2021-09-01 2017-02-01 1944-8244 https://pubs.kist.re.kr/handle/201004/123092 A new methodology for fabrication of inorganic organic hybrid ionogels and scaffolds is developed through facile cross-linking and solution extraction of a newly developed ionic polyhedral oligomeric silsesquioxane with inorganic core. Through design of various cationic tertiary amines, as well as cross-linkable functional groups on each arm of the inorganic core, high-performance ionogels are fabricated with excellent electrochemical stability and unique ion conduction behavior, giving superior lithium ion battery performance. Moreover, through solvent extraction of the liquid components, hybrid scaffolds with well-defined, interconnected mesopores are utilized as heterogeneous catalysts for the CO2-catalyzed cycloaddition of epoxides. Excellent catalytic performance, as well as highly efficient recyclability are observed when compared to other previous literature materials. English American Chemical Society LIQUID ELECTROLYTES BATTERIES NANOPARTICLES EFFICIENT IONOGELS SILICA Multifunctional Mesoporous Ionic Gels and Scaffolds Derived from Polyhedral Oligomeric Silsesquioxanes Article 10.1021/acsami.6b12340 1 ACS Applied Materials & Interfaces, v.9, no.4, pp.3616 - 3623 ACS Applied Materials & Interfaces 9 4 3616 3623 scie scopus 000393355900042 2-s2.0-85011840641 Nanoscience & Nanotechnology Materials Science, Multidisciplinary Science & Technology - Other Topics Materials Science Article LIQUID ELECTROLYTES BATTERIES NANOPARTICLES EFFICIENT IONOGELS SILICA ionic transport ionogel polyhedral oligomeric silsesquioxane porous materials supported ionic liquids heterogeneous catalyst