Jaiswal, Shivendra Kumar Choi, Sung Min Hong, Jongsup Yoon, Kyung Joong Son, Ji-Won Kim, Byung-Kook Lee, Hae-Weon Lee, Jong-Ho 2024-01-20T02:34:41Z 2024-01-20T02:34:41Z 2021-09-05 2016-12 0947-7047 https://pubs.kist.re.kr/handle/201004/123374 Proton-conducting ceramics have been very useful due to their potential applications in fuel cells, electrolysers, and hydrogen membranes. The proton-conducting fuel cell electrolytes (Ba1-x Sr (x) )(Ce0.75Zr0.10Y0.15)O3-delta (x = 0-1.0) have been synthesized through sol-gel method and characterized with regard to phase, structural stability, and electrical conductivity. The structural behavior has been investigated by X-ray diffraction and theRaman spectroscopy. The XRD analysis shows perovskite-type cubic structure and values of lattice parameter lie in the range of similar to 4.29 to similar to 4.40 . Strontium substitution leads to lattice contraction, strengthening of the metal-oxygen bond, and increase of oxygen content (3-delta). The Raman spectra show different types of stretching/vibrations corresponding to octahedral, M-O stretching, and oxygen vacancies. The electrical conduction was found to be protonic in nature and decreases with increase of strontium insertion. The composition x = 0.4 shows relatively better structural stability against humid air/boiling water condition while inferior in carbon dioxide atmosphere. English SPRINGER HEIDELBERG DOPED BARIUM ZIRCONATE CHEMICAL-STABILITY PROTON CONDUCTOR OPTICAL-ABSORPTION PHASE NONSTOICHIOMETRY TRANSPORT MEMBRANE BEHAVIOR GD On the sol-gel synthesis and characterization of (BaSr)(CeZr)O-3-based fuel cell electrolytes Article 10.1007/s11581-016-1801-3 1 IONICS, v.22, no.12, pp.2529 - 2538 IONICS 22 12 2529 2538 scie scopus 000389205600030 2-s2.0-84982267569 Chemistry, Physical Electrochemistry Physics, Condensed Matter Chemistry Electrochemistry Physics Article DOPED BARIUM ZIRCONATE CHEMICAL-STABILITY PROTON CONDUCTOR OPTICAL-ABSORPTION PHASE NONSTOICHIOMETRY TRANSPORT MEMBRANE BEHAVIOR GD Proton conductor Solid electrolyte (Ba1-xSrx)(Ce0.75Zr0.10Y0.15)O3-delta Sol-gel synthesis Raman spectroscopy Stability