Lee, Jae Hun Jung, Jung Pyo Jang, Eunji Lee, Ki Bong Hwang, Yun Jeong Min, Byoung Koun Kim, Jong Hak 2024-01-20T03:01:17Z 2024-01-20T03:01:17Z 2021-09-05 2016-11-15 0376-7388 https://pubs.kist.re.kr/handle/201004/123429 Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) is a widely used conductive polymer in various electronic devices. Here we report the first use of PEDOT-PSS to enhance CO2 capture performance of all-polymeric membranes. Specifically, an amphiphilic comb copolymer, i.e. poly(2-[-3(2H-benzotriazol-2-yl)-4-hydroxyphenyll ethyl methacrylate)-poly(oxyethylene methacrylate) (PBEMPOEM or PBE), was synthesized to disperse PEDOT-PSS chains. Isolated and aggregated PEDOT-PSS transformed into an interconnected network structure upon combination with PBE, due to specific interactions. Incorporation of PEDOT-PSS generated a facile pathway for enhanced diffusive transport, resulting in improved CO2 and N-2 permeability. However, CO2 permeability increased more significantly due to enhanced CO2 solubility, resulting in slight increase in CO2/N-2 selectivity. The PBE membrane containing PEDOT-PSS 5 wt% showed the highest performance with a CO2 permeability of 59.6 Barrer and CO2/N-2 selectivity of 77.4. The performance of PBE/PEDOT-PSS membranes was very close to the 2008 Robeson upper bound and much higher than those of PBE/PEDOT, PBE/PSS and commercial PEBAX membranes. (C) 2016 Elsevier B.V. All rights reserved. English ELSEVIER SCIENCE BV MIXED-MATRIX MEMBRANES GAS SEPARATION PROPERTIES ORGANIC FRAMEWORK COMPOSITE MEMBRANES PERFORMANCE SELECTIVITY ADSORPTION POLYIMIDE PEG PEDOT-PSS embedded comb copolymer membranes with improved CO2 capture Article 10.1016/j.memsci.2016.06.025 1 JOURNAL OF MEMBRANE SCIENCE, v.518, pp.21 - 30 JOURNAL OF MEMBRANE SCIENCE 518 21 30 scie scopus 000382254500003 2-s2.0-84978539338 Engineering, Chemical Polymer Science Engineering Polymer Science Article MIXED-MATRIX MEMBRANES GAS SEPARATION PROPERTIES ORGANIC FRAMEWORK COMPOSITE MEMBRANES PERFORMANCE SELECTIVITY ADSORPTION POLYIMIDE PEG CO2 capture Gas separation Membrane Conducting polymer Graft copolymer