Cheong, Sanghyuk Kim, Jai-Kyeong Cho, Jinhan 2024-01-20T03:03:08Z 2024-01-20T03:03:08Z 2021-09-03 2016-11 2040-3364 https://pubs.kist.re.kr/handle/201004/123531 There is rising demand for metal or metal oxide nanoparticle (NP)/polymer nanocomposite films with desired functionalities. However, it is difficult to directly combine well-defined NPs synthesized using organic fatty acids in nonpolar media with water-soluble polymers, except polyelectrolytes with specific functional moieties, because they differ in their hydrophobic/hydrophilic properties. We have developed a facile and universal hydrophilic/hydrophobic layer-by-layer (LbL) assembly method that enables perfect nanoblending between water-soluble polymers and hydrophobic NPs, maintaining their specific functionalities. Various hydrophobic NPs stabilized by using oleic acid (OA) (e.g., OA-TiO2, OA-Fe3O4, OA-Ag, and OA-Pt NPs) were directly LbL assembled with various water-soluble polymers (including biomaterials) containing carboxylic acid (-COOH), tertiary ammonium (N+), hydroxyl (-OH), and/or ether (-O-) groups. This adsorption behavior is based on the affinities between water-soluble polymers with multidentate binding sites and the surfaces of metal or metal oxide NPs stabilized by OA ligands. Our approach can be used to fabricate unipolar switching nonvolatile memory devices with ON/OFF current ratios greater than similar to 10(10) and good memory stability, despite the use of water-soluble polymers. English ROYAL SOC CHEMISTRY BY-LAYER GROWTH NUCLEOPHILIC-SUBSTITUTION MULTILAYER FILMS THIN-FILMS MEDIA NANOCRYSTALS RECOGNITION ADSORPTION DIODES ACIDS Functional nanocomposites with perfect nanoblending between water-soluble polymers and hydrophobic inorganic nanoparticles: applications to electric-stimuli-responsive films Article 10.1039/c6nr05007g 1 NANOSCALE, v.8, no.43, pp.18315 - 18325 NANOSCALE 8 43 18315 18325 scie scopus 000387858400009 2-s2.0-84994613459 Chemistry, Multidisciplinary Nanoscience & Nanotechnology Materials Science, Multidisciplinary Physics, Applied Chemistry Science & Technology - Other Topics Materials Science Physics Article BY-LAYER GROWTH NUCLEOPHILIC-SUBSTITUTION MULTILAYER FILMS THIN-FILMS MEDIA NANOCRYSTALS RECOGNITION ADSORPTION DIODES ACIDS