Wijaya, Yanuar Philip Kristianto, Ivan Lee, Hyunjoo Jae, Jungho 2024-01-20T03:03:36Z 2024-01-20T03:03:36Z 2021-09-05 2016-10-15 0016-2361 https://pubs.kist.re.kr/handle/201004/123554 The Diels-Alder cycloaddition of biomass-derived furans and subsequent dehydrative aromatization are potentially valuable processes for the sustainable production of aromatic chemicals from biomass. In this paper, we have investigated the catalytic activity of a series of homogeneous and heterogeneous Lewis acid catalysts in connection with the conversion of biomass-derived 2-methylfuran (MF) and ethylene to toluene. We have used a number of Lewis acid metal chlorides, cation-exchanged Y zeolites, Sn- and Zr-containing beta zeolites to understand the role of acid sites and activity correlation in the MF reaction. The Lewis acid catalysts of AlCl3 and Na-Y zeolite demonstrated superior selectivity for toluene production with regard to the Bronsted acidic zeolites of H-Beta and H-Y, which have proven to be effective for the conversion of 2,5-dimethylfuran (DMF) to p-xylene. The high toluene selectivity of the Lewis acid catalysts was mainly attributed to their ability to retard side reactions, such as oligomerization and allcylation, as well as to accelerate the cycloaddition of MF and ethylene. In the case of Bronsted acidic zeolites, the side reactions were significantly enhanced, resulting in lower selectivity to toluene. The catalytic activity of the Lewis acidic metal chloride catalysts was correlated with an empirical scale of Lewis acid strength, showing that the strongest Lewis acid, AlCl3, gave the highest toluene yield of similar to 70% at 250 degrees C after 24 h. Similarly, of the alkali cation-exchanged Y-zeolites investigated here, Li- and Na-Y were more active than K- and Cs-Y due to the smaller size of the cations, resulting in stronger Lewis acidity. Na-Y was also more active than Sn- and Zr-Beta, which have framework Lewis acidic sites, demonstrating its superiority for catalyzing the cascade of Diels-Alder and dehydrative English ELSEVIER SCI LTD P-XYLENE PRODUCTION SN-BETA ETHYLENE CYCLOADDITION DIMETHYLFURAN AROMATICS 2,5-DIMETHYLFURAN AROMATIZATION ACCELERATION CONVERSION Production of renewable toluene from biomass-derived furans via Diels-Alder and dehydration reactions: A comparative study of Lewis acid catalysts Article 10.1016/j.fuel.2016.06.010 1 FUEL, v.182, pp.588 - 596 FUEL 182 588 596 scie scopus 000379102600064 2-s2.0-84973861548 Energy & Fuels Engineering, Chemical Energy & Fuels Engineering Article P-XYLENE PRODUCTION SN-BETA ETHYLENE CYCLOADDITION DIMETHYLFURAN AROMATICS 2,5-DIMETHYLFURAN AROMATIZATION ACCELERATION CONVERSION Biomass Diels-Alder Lewis acid Furan Toluene