Van Chinh Hoang VanDung Do Nah, In Wook Lee, Chongmok Cho, Won Il Oh, In Hwan 2024-01-20T03:33:22Z 2024-01-20T03:33:22Z 2021-09-04 2016-08-20 0013-4686 https://pubs.kist.re.kr/handle/201004/123780 Li2S with theoretical capacity of 1166 mAh g (1) has been considered as a promising candidate for Li-S cathode as it could be paired with safer Li-free electrodes to resolve safety issues. However, the success is hindered by the nature of Li2S and corresponding reduction species, including low conductivity and the shuttling phenomenon. Herein, we simply coat graphene films directly onto the Li2S cathode, which can suppress polysulfides dissolution effectively. The electrochemical performance of the cathode depending on graphene interlayer thickness (0, 20, 45, 54, 77 and 88 mu m) has been investigated. Li2S cathode with the 45 pm thick interlayer exhibits initial discharge capacity of 1029.21 mAh g (1) and 779.74 mAh g (1) at 0.05C and 0.1C, respectively, and capacity retention of above 60% with coulombic efficiency of around 90% over 300 cycles at high C rates. The results are discussed in terms of the graphene film thickness and the conductivity of the film as well as Li ion diffusivity. (C) 2016 Published by Elsevier Ltd. English PERGAMON-ELSEVIER SCIENCE LTD COMPOSITE CATHODES CARBON ION NANOFIBERS PAPER Facile Coating of Graphene Interlayer onto Li2S as a High Electrochemical Performance Cathode for Lithium Sulfur Battery Article 10.1016/j.electacta.2016.04.171 1 ELECTROCHIMICA ACTA, v.210, pp.1 - 6 ELECTROCHIMICA ACTA 210 1 6 scie scopus 000380746100001 2-s2.0-84973351686 Electrochemistry Electrochemistry Article COMPOSITE CATHODES CARBON ION NANOFIBERS PAPER Lithium sulfide cathodes graphene lithium sulfur batteries Li ion diffusivity