Hussain, Muhammad Asif Yang, MinHo Jang, Hyung-Seok Hwang, Sung-Yeon Um, Byung-Hun Choi, Bong Gill Kim, Jung Won 2024-01-20T04:01:53Z 2024-01-20T04:01:53Z 2021-09-05 2016-06-29 0888-5885 https://pubs.kist.re.kr/handle/201004/123943 A highly efficient two-dimensional (2D) nanocatalyst for the aerobic oxidation of amines, consisting of ruthenium-exfoliated molybdenum disulfide (Ru@E-MoS2), was investigated. As-synthesized Ru@E-MoS2 yielded the nitriles from various aromatic, aliphatic, allylic, and heteroatomic amines with high selectivity in molecular oxygen as terminal oxidants. The Ru@E-MoS2 experienced an improved catalytic activity for benzylamine and p-substituted benzylamine derivatives and produced good turnover numbers (TONs) for aliphatic amines. Moreover, the heterogeneous Ru@E-MoS2 nanocatalyst maintained its catalytic performance for five cycles of benzylamine oxidation reaction. English AMER CHEMICAL SOC CATALYTIC-ACTIVITY EFFICIENT OXIDE DEHYDROGENATION BENZYLAMINES COMPLEX OXYGEN Two-Dimensional Heterogeneous Ruthenium-Molybdenum Disulfide Nanocatalyst for the Selective Aerobic Oxidation of Amines Article 10.1021/acs.iecr.5b04162 1 INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.55, no.25, pp.7043 - 7047 INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 55 25 7043 7047 scie scopus 000378984600016 2-s2.0-84976638018 Engineering, Chemical Engineering Article CATALYTIC-ACTIVITY EFFICIENT OXIDE DEHYDROGENATION BENZYLAMINES COMPLEX OXYGEN