Kang, Jin-Kyu Kim, Jae-Hyun Kim, Song-Bae Lee, Sang-Hyup Choi, Jae-Woo Lee, Chang-Gu 2024-01-20T04:30:22Z 2024-01-20T04:30:22Z 2021-09-05 2016-05 1944-3994 https://pubs.kist.re.kr/handle/201004/124105 The aim of this study was to investigate the removal of phosphate (P) using ammonium-functionalized MCM-41 (A-MCM-41). Batch experiments were performed with A-MCM-41 under various conditions including the adsorbent dose, reaction time, initial P concentration, and solution pH. The results showed that the phosphate removal in the MCM-41 (initial P conc.=2mgPL(-1)) was negligible with the percent removal of 1.0% at the adsorbent dosages between 0.5 and 2.0gL(-1). In the case of A-MCM-41, the percent removal increased from 73.6 to 100% as the adsorbent dose increased from 0.5 to 2.0gL(-1). This indicated an enhancement of the phosphate removal due to the surface modification of the MCM-41 through the functionalization of the ammonium group (NH3+). The results also demonstrated that the phosphate removal by the MCM-41 was minimal throughout the acidic and alkaline pH conditions (3.1% at pH 3.5; 1.0% at pH 5.4-10.7), whereas the phosphate removal by the A-MCM-41 was effective throughout the acidic and neutral pH values (94.7-97.6% at pH 3.5-7.4). In highly alkaline conditions, however, the phosphate removal by the A-MCM-41 was greatly reduced (3.4% at pH 10.7) due to the competition of the hydroxyl groups (OH-) with phosphate ions for sorption sites. The results indicated that the pseudo-second-order model was most suitable for describing the kinetic data with the parameter values of q(e)=1.86mgPg(-1) and k(2)=183.98gmgP(-1)h(-1). The Redlich-Peterson isotherm fits well with the equilibrium data, with the parameter values of K-R/a(R)=7.90mgPg(-1) and g=0.83. English DESALINATION PUBL Ammonium-functionalized mesoporous silica MCM-41 for phosphate removal from aqueous solutions Article 10.1080/19443994.2015.1038590 1 DESALINATION AND WATER TREATMENT, v.57, no.23, pp.10839 - 10849 DESALINATION AND WATER TREATMENT 57 23 10839 10849 N scie scopus 000371183300035 2-s2.0-84958892690 Engineering, Chemical Water Resources Engineering Water Resources Article ONE-POT SYNTHESIS NITRATE ANIONS SURFACE-STRUCTURE ADSORPTION RECOVERY PHOSPHORUS EFFICIENT BEHAVIOR IONS Mesoporous silica MCM-41 Phosphate Sorption Surface functionalization