Choi, Mugyeom Koppala, Siva Kumar Yoon, Dohyeon Hwang, Jieun Kim, Seung Min Kim, Jaehoon 2024-01-20T04:33:31Z 2024-01-20T04:33:31Z 2021-09-05 2016-03-31 0378-7753 https://pubs.kist.re.kr/handle/201004/124271 A simple and effective approach for the tight anchoring of molybdenum disulfide (MoS2) to the surface of supercritical-alcohol-reduced graphene oxide (SRGO) is developed. The MoS2-SRGO composites are synthesized by the one-pot deposition of MoO2 on SRGO and simultaneous reduction of GO to SRGO in supercritical methanol followed by sulfurization. The obtained MoS2-SRGO composites contain a crystalline MoS2 phase comprising 11-14 layers of MoS2. In addition, the composites have mesoporous structures with high porosities, ranging between 55 and 57%. In comparison with bare MoS2 and SRGO, the MoS2-SRGO composites have enhanced electrochemical performances due to their mesoporous structures and the synergetic effect between MoS2 and SRGO sheets. When tested as the anode in a secondary lithium battery, it shows high reversible capacity of 896 mAh g(-1) at 50 mA g(-1) after 50 cycles, a high rate capacity of 320 mAh g(-1) at a high charge-discharge rate of 2.5 A g(-1), and long-term cycling of 724 mAh g(-1) at 50 mA g(-1) after 200 cycles. This unique synthetic approach effectively and tightly anchors MoS2 nanoparticles to the SRGO surface, resulting in improved structural integrity, electron transfer efficiency between the SRGO sheets and MoS2, and Li-ion diffusion kinetics. Crown Copyright (C) 2016 Published by Elsevier B.V. All rights reserved. English ELSEVIER SCIENCE BV ORDERED MESOPOROUS MOS2 SULFUR-DOPED GRAPHENE ANODE MATERIALS CATALYTIC COMBUSTION GRAPHITE OXIDE DIESEL SOOT LITHIUM NANOPARTICLES NANOSHEETS NANOCOMPOSITES A route to synthesis molybdenum disulfide-reduced graphene oxide (MoS2-RGO) composites using supercritical methanol and their enhanced electrochemical performance for Li-ion batteries Article 10.1016/j.jpowsour.2016.01.081 1 JOURNAL OF POWER SOURCES, v.309, pp.202 - 211 JOURNAL OF POWER SOURCES 309 202 211 scie scopus 000371549100023 2-s2.0-84957077132 Chemistry, Physical Electrochemistry Energy & Fuels Materials Science, Multidisciplinary Chemistry Electrochemistry Energy & Fuels Materials Science Article ORDERED MESOPOROUS MOS2 SULFUR-DOPED GRAPHENE ANODE MATERIALS CATALYTIC COMBUSTION GRAPHITE OXIDE DIESEL SOOT LITHIUM NANOPARTICLES NANOSHEETS NANOCOMPOSITES Supercritical alcohol Molybdenum disulfide Reduced graphene oxide Composites Lithium-ion battery