Yoon, Ji Sun Choi, Jae-Wook Suh, Dong Jin Lee, Kangtaek Lee, Hyunjoo Ha, Jeong-Myeong 2024-01-20T06:04:11Z 2024-01-20T06:04:11Z 2021-09-05 2015-09-01 1867-3880 https://pubs.kist.re.kr/handle/201004/125035 Water, which frequently inhibits organic reactions, improves the hydrodeoxygenation activity of lignin-derived guaiacol on a bifunctional catalyst of Rh/SiO2-Al2O3 in a biphasic mixture of n-decane and water. The unique properties of subcritical water appear to promote hydrodeoxygenation, which improves the production of monooxygenates by removing more oxygen atoms of guaiacol while suppressing the formation of fully deoxygenated hydrocarbons because of the poor solubility of hydrophobic monooxygenates. English WILEY-V C H VERLAG GMBH ORGANIC-REACTIONS PROTON-TRANSFER CATALYTIC CONVERSION SUBCRITICAL WATER TRANSITION-STATE ACID CATALYST SOLID ACID BIO-OILS CYCLOHEXANONE BIOMASS Water-Assisted Selective Hydrodeoxygenation of Lignin-Derived Guaiacol to Monooxygenates Article 10.1002/cctc.201500345 1 CHEMCATCHEM, v.7, no.17, pp.2669 - 2674 CHEMCATCHEM 7 17 2669 2674 scie scopus 000360821200016 2-s2.0-84940723439 Chemistry, Physical Chemistry Article ORGANIC-REACTIONS PROTON-TRANSFER CATALYTIC CONVERSION SUBCRITICAL WATER TRANSITION-STATE ACID CATALYST SOLID ACID BIO-OILS CYCLOHEXANONE BIOMASS biomass biphasic catalysis hydrogenation rhodium water