Cho, Kangwoo Hoffmann, Michael R. 2024-01-20T07:31:56Z 2024-01-20T07:31:56Z 2021-09-05 2015-03-24 0897-4756 https://pubs.kist.re.kr/handle/201004/125647 Ir(0.7)Ta(0.3)Oy/BixTi1-xOz heterojunction anodes have been developed and characterized for reactive chlorine species (RCS) generation in dilute aqueous solution (50 mM NaCl). The primary objective of the research was to control the electro-stationary speciation of hydrous metal oxides between hydroxyl radical (>MOx(OH)) and higher valence-state oxides (>MOx+1). An underlying layer of the mixed-metal oxide, Ir0.7Ta0.3Oy, was synthesized to serve as a primary ohmic contact and electron shuttle. Binary thin films of BixTi1-xOz were prepared from the thermal decomposition of an aqueous solution mixture of Ti/Bi complexes. With these core components, the measured current efficiency for RCS generation (eta(RCS)) was enhanced where the values observed for x = 0.1 or 0.3 were twice of the eta(RCS) of the Ir0.7Ta0.3Oy anode. At the same time, the rates of RCS generation were enhanced by factors of 20 - 30%. Partial substitution of Ti with Bi results in a positive shift in surface charge allowing for stronger interaction with anions as confirmed by FTIR-ATR analysis. A kinetic model to describe the formate ion degradation showed that an increasing fraction of Bi in the composite promotes a redox transition of >MOx(OH) to >MOx+1. In accelerated life tests under conditions corresponding to a service life of 2 years under an operational current density of 300 A m-2, dissociation of Ti component from Ir0.7Ta0.3Oy/TiO2 was found to be minimal, while BixTi(1-x)O(z) in the surface layers undergoes oxidation and a subsequent dissolution. English AMER CHEMICAL SOC OXYGEN EVOLUTION REACTION WASTE-WATER TREATMENT ORGANIC POLLUTANTS OXIDE ELECTRODES ACID-SOLUTION BI2O3 OXIDATION TIO2 ELECTROCATALYSTS SUPERCAPACITORS BixTi1-xOz Functionalized Heterojunction Anode with an Enhanced Reactive Chlorine Generation Efficiency in Dilute Aqueous Solutions Article 10.1021/acs.chemmater.5b00376 1 CHEMISTRY OF MATERIALS, v.27, no.6, pp.2224 - 2233 CHEMISTRY OF MATERIALS 27 6 2224 2233 scie scopus 000351971600041 2-s2.0-84925835296 Chemistry, Physical Materials Science, Multidisciplinary Chemistry Materials Science Article OXYGEN EVOLUTION REACTION WASTE-WATER TREATMENT ORGANIC POLLUTANTS OXIDE ELECTRODES ACID-SOLUTION BI2O3 OXIDATION TIO2 ELECTROCATALYSTS SUPERCAPACITORS Electrode Heterojunction Reactive Chlorine Water Treatment