Elsawy, Walaa Son, Myungwoo Jang, Jisu Kim, Myung Jin Ji, Yongsung Kim, Tae-Wook Ko, Heung Cho Elbarbary, Ahmed Ham, Moon-Ho Lee, Jae-Suk 2024-01-20T07:33:38Z 2024-01-20T07:33:38Z 2021-09-04 2015-03 2161-1653 https://pubs.kist.re.kr/handle/201004/125737 Nonvolatile resistive memory devices based on a new low bandgap donor acceptor (D-A) conjugated polymer, poly((E)-6,6'-bis(2,3-dihydrothieno[3,4-b] [1,4] dioxine-5-y1) -1,1'-bis (2-octyldo decyl)-[3,3'-biindolinyi-dene3-2,2'-dione) (PIDED), which are fabricated and operated in ambient air, are reported. The D-A conjugated polymer is synthesized from 2,3dihydrothieno[3,4-b][1,4]dioxine and isoindigo as an electron donor and an electron acceptor, respectively, using CH-arylation polymerization. The devices show nonvolatile, unipolar resistive switching behaviors with a high on/off current ratio (similar to 10(4)), excellent endurance cycles (>200 cycles), and a long retention time (>10(4) s) in ambient air. These properties remain stable in ambient air over one year, demonstrating that the device performance is significantly unaffected by exposure to air as the isoindigo has strong electron-withdrawing character and the PIDED exhibits a high degree of crystallinity. This study may pave the way for use of practical nonvolatile organic memory devices operating in ambient air. English AMER CHEMICAL SOC FIELD-EFFECT TRANSISTORS RESISTIVE MEMORY THIN-FILM PERFORMANCE INTEGRATION MECHANISM COPOLYMER lsoindigo-Based Donor-Acceptor Conjugated Polymers for Air-Stable Nonvolatile Memory Devices Article 10.1021/mz500698p 1 ACS MACRO LETTERS, v.4, no.3, pp.322 - 326 ACS MACRO LETTERS 4 3 322 326 scie scopus 000351326100012 2-s2.0-84925002854 Polymer Science Polymer Science Article FIELD-EFFECT TRANSISTORS RESISTIVE MEMORY THIN-FILM PERFORMANCE INTEGRATION MECHANISM COPOLYMER Organic memory conjugated polymer