Kang, Min-Gyu Cho, Kwang-Hwan Kim, Jin-Sang Nahm, Sahn Yoon, Seok-Jin Kang, Chong-Yun 2024-01-20T09:32:33Z 2024-01-20T09:32:33Z 2021-09-04 2014-07 1359-6454 https://pubs.kist.re.kr/handle/201004/126669 Cobalt oxide-based Ca3Co4O9 ceramics are known for their good thermoelectric (TE) performance and chemical stability at high temperatures (<900 degrees C); however, the crystalline phase of these ceramics is unstable beyond 926 degrees C due to thermal decomposition. This low limit (926 degrees C) on the sintering temperature produces a very low-density material with poor TE properties. Here, a novel method (post-calcination) to synthesize high-density and single-phase Ca3Co4O9 ceramics is investigated by high-temperature X-ray diffraction analysis. The post-calcination method, which includes cooling and reheating of the phase decomposed Ca3Co4O9 ceramics, synthesizes high-density (relative density = 92%) and single-phase Ca3Co4O9 ceramics via a solid-state reaction at a high sintering temperature of 1200 degrees C, and improved TE properties (power factor = 0.245 mW K-2 in 1 at 800 degrees C) are observed. The post-calcination method is expected to be applicable to Ca3Co4O9 and other materials that are difficult to obtain in high-density form due to thermal decomposition. Furthermore, this technique improves the sinterability and production efficiency without using complicated processes. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. English PERGAMON-ELSEVIER SCIENCE LTD MISFIT-LAYERED COBALTITE CA3CO4O9 ENHANCEMENT THERMODYNAMICS THERMOPOWER PERFORMANCE FABRICATION TRANSITION CO3O4 POWER Post-calcination, a novel method to synthesize cobalt oxide-based thermoelectric materials Article 10.1016/j.actamat.2014.04.008 1 ACTA MATERIALIA, v.73, pp.251 - 258 ACTA MATERIALIA 73 251 258 scie scopus 000337853100024 2-s2.0-84899662545 Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Materials Science Metallurgy & Metallurgical Engineering Article MISFIT-LAYERED COBALTITE CA3CO4O9 ENHANCEMENT THERMODYNAMICS THERMOPOWER PERFORMANCE FABRICATION TRANSITION CO3O4 POWER Ca3Co4O9 Phase decomposition Sintering Thermoelectrics