Jun, Jin-Woo Suh, Young-Woong Suh, Dong Jin Lee, Yong-Kul 2024-01-20T11:03:02Z 2024-01-20T11:03:02Z 2021-09-05 2013-11-25 1226-086X https://pubs.kist.re.kr/handle/201004/127431 Six-carbon containing model compounds of 1-hexanol, 1,6-hexanediol and sorbitol for the reforming were employed to study the effect of hydroxyl functional group on the thermodynamic equilibrium product distribution in a wide range of conditions of temperature (300-1300 K), pressure (1-150 atm) and feed composition (H2O/carbon = 0.5-30). The increase of hydroxyl group in reactants gave rise to the increase of carbon dioxide with loss of methane in the product in the following order: sorbitol > 1,6hexanediol > 1-hexanol, while the formation of hydrogen and carbon monoxide was mostly governed by the feed composition (H2O/carbon) and pressure rather than the number of hydroxyl group in reactants. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. English ELSEVIER SCIENCE INC BIOMASS-DERIVED HYDROCARBONS OXYGENATED HYDROCARBONS HYDROGEN-PRODUCTION BIO-OIL FUEL CATALYSTS SORBITOL ALKANES Thermodynamic analysis of steam and aqueous reforming of hydroxylated C6 aliphatic compounds Article 10.1016/j.jiec.2013.03.020 1 JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, v.19, no.6, pp.2072 - 2078 JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 19 6 2072 2078 scie scopus kci ART001820129 000326317200045 2-s2.0-84883795712 Chemistry, Multidisciplinary Engineering, Chemical Chemistry Engineering Article BIOMASS-DERIVED HYDROCARBONS OXYGENATED HYDROCARBONS HYDROGEN-PRODUCTION BIO-OIL FUEL CATALYSTS SORBITOL ALKANES Thermodynamic analysis 1-Hexanol 1,6-Hexanediol Sorbitol Reforming