Kim, Taehee Wooh, Sanghyuk Son, Jeong Gon Char, Kookheon 2024-01-20T11:05:05Z 2024-01-20T11:05:05Z 2021-09-04 2013-10-22 0024-9297 https://pubs.kist.re.kr/handle/201004/127536 We investigate orientation and lateral ordering of poly(styrene-block-methyl methacrylate) (PS-b-PMMA) diblock copolymer (diBCP) thin films placed on ordered nanoparticle (NP) monolayers. The densely packed NP monolayers were prepared on silicon substrates with the Langmuir-Blodgett (LB) deposition technique. The perpendicular domain orientation of BCP thin films is obtained on the ordered NP monolayers due to the nanoscale regular roughness which exerts the elastic deformation on the BCP nanodomains and suppresses the substrate-induced parallel orientation. The effect of BCP film thickness as well as the NP size on the orientation of BCP nanodomains was systematically investigated. We also demonstrate the defect-tolerant ordering perpendicular orientation of BCP thin films on the NP-vacant sites. English AMER CHEMICAL SOC LITHOGRAPHY ARRAYS GRAPHENE LAMELLAE Orientation Control of Block Copolymer Thin Films Placed on Ordered Nanoparticle Mono layers Article 10.1021/ma401601f 1 MACROMOLECULES, v.46, no.20, pp.8144 - 8151 MACROMOLECULES 46 20 8144 8151 scie scopus 000326209400009 2-s2.0-84886602003 Polymer Science Polymer Science Article LITHOGRAPHY ARRAYS GRAPHENE LAMELLAE block copolymer microdomain nanopatterns perpendicular orientation