Song, Jung Ho Kim, Taejung Lee, Jae Wook Moon, Soo-Yeon Kim, Won-Suk Ham, Jungyeob 2024-01-20T11:34:55Z 2024-01-20T11:34:55Z 2021-09-04 2013-08-12 1615-4150 https://pubs.kist.re.kr/handle/201004/127775 A series of di- or trisubstituted alkene-containing potassium organotrifluoroborates was prepared from the corresponding haloaryltrifluoroborates via palladium-catalyzed Heck-Mizoroki reaction with various olefins in good to excellent yields. Furthermore, the Suzuki-Miyaura cross-coupling reaction of these alkenylaryltrifluoroborates was successfully carried out with aryl and alkenyl bromides using 5mol% of tetrakis(triphenylphosphine)palladium(0) and 3.0equiv. of cesium carbonate in aqueous 1,4-dioxane under microwave irradiation. English WILEY-V C H VERLAG GMBH CROSS-COUPLING REACTIONS N-HETEROCYCLIC CARBENES SUZUKI-MIYAURA ANIONIC-POLYMERIZATION PALLADIUM COMPLEXES ARYL CHLORIDES CATALYZED HECK BORONIC ACIDS EFFICIENT LIGANDS Potassium (E)-Alkenylaryltrifluoroborates: Orthogonal Functionalization of Haloaryltrifluoroborates via Heck-Mizoroki Reaction Article 10.1002/adsc.201300294 1 ADVANCED SYNTHESIS & CATALYSIS, v.355, no.11-12, pp.2459 - 2465 ADVANCED SYNTHESIS & CATALYSIS 355 11-12 2459 2465 scie scopus 000327799600040 2-s2.0-84884503291 Chemistry, Applied Chemistry, Organic Chemistry Article CROSS-COUPLING REACTIONS N-HETEROCYCLIC CARBENES SUZUKI-MIYAURA ANIONIC-POLYMERIZATION PALLADIUM COMPLEXES ARYL CHLORIDES CATALYZED HECK BORONIC ACIDS EFFICIENT LIGANDS Heck-Mizoroki reaction microwave irradiation potassium (E)-alkenylaryltrifluoroborates Suzuki-Miyaura reaction