Wang, Ling Yun Lee, Hwa Young Lee, Man Seung 2024-01-20T12:01:06Z 2024-01-20T12:01:06Z 2021-09-05 2013-08 1345-9678 https://pubs.kist.re.kr/handle/201004/127830 Solvent extraction of Zr and Hf from hydrochloric acid solution was performed by using acidic organophosphorus extractants and their mixtures with TOPO. hi the HCl concentration range from 1 to 4 mol/dm(3), solvation reaction was responsible for the extraction of Zr and Hf by single acidic organophosphorus extractants, such as D2EHPA, PC88A and Cyanex272. Although the extraction percentage of both metals by single and mixture of extractants increased with the increase of HCl concentration, the dependence of separation factor on the HCl concentration showed opposite behavior in both extractant systems. Synergistic extraction of Zr and Hf was obtained by the mixtures. Single Cyanex272 and a mixture of Cyanex272 and TOPO were found to be the most efficient in separating the two metals. English JAPAN INST METALS & MATERIALS SEPARATION ZR BEHAVIOR NB HF Solvent Extraction of Zirconium and Hafnium from Hydrochloric Acid Solutions Using Acidic Organophosphorus Extractants and Their Mixtures with TOPO Article 10.2320/matertrans.M2013150 1 MATERIALS TRANSACTIONS, v.54, no.8, pp.1460 - 1466 MATERIALS TRANSACTIONS 54 8 1460 1466 scie scopus 000325122900038 2-s2.0-84883195521 Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Materials Science Metallurgy & Metallurgical Engineering Article SEPARATION ZR BEHAVIOR NB HF zirconium hafnium acidic organophosphorus extractant trioctylphosphine oxide (TOPO) synergism